{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T21:06:16Z","timestamp":1792098376029,"version":"4.4.0"},"reference-count":27,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2014,11,24]],"date-time":"2014-11-24T00:00:00Z","timestamp":1416787200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,1,19]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Nitrogenase cofactors can be extracted into an organic solvent to catalyze the reduction of cyanide (CN<jats:sup>\u2212<\/jats:sup>), carbon monoxide (CO), and carbon dioxide (CO<jats:sub>2<\/jats:sub>) without using adenosine triphosphate (ATP), when samarium(II) iodide (SmI<jats:sub>2<\/jats:sub>) and 2,6\u2010lutidinium triflate (Lut\u2010H) are employed as a reductant and a proton source, respectively. Driven by SmI<jats:sub>2<\/jats:sub>, the cofactors catalytically reduce CN<jats:sup>\u2212<\/jats:sup> or CO to C<jats:sub>1<\/jats:sub>\u2013C<jats:sub>4<\/jats:sub> hydrocarbons, and CO<jats:sub>2<\/jats:sub> to CO and C<jats:sub>1<\/jats:sub>\u2013C<jats:sub>3<\/jats:sub> hydrocarbons. The C\uf8ffC coupling from CO<jats:sub>2<\/jats:sub> indicates a unique Fischer\u2013Tropsch\u2010like reaction with an atypical carbonaceous substrate, whereas the catalytic turnover of CN<jats:sup>\u2212<\/jats:sup>, CO, and CO<jats:sub>2<\/jats:sub> by isolated cofactors suggests the possibility to develop nitrogenase\u2010based electrocatalysts for the production of hydrocarbons from these carbon\u2010containing compounds.<\/jats:p>","DOI":"10.1002\/anie.201410412","type":"journal-article","created":{"date-parts":[[2014,11,24]],"date-time":"2014-11-24T21:14:55Z","timestamp":1416863695000},"page":"1219-1222","source":"Crossref","is-referenced-by-count":61,"title":["Catalytic Reduction of CN<sup>\u2212<\/sup>, CO, and CO<sub>2<\/sub> by Nitrogenase Cofactors in Lanthanide\u2010Driven Reactions"],"prefix":"10.1002","volume":"54","author":[{"given":"Chi Chung","family":"Lee","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilin","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus 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turnover number (TON) reflects the total number of carbon atoms that appear in the various carbon\u2010containing products."},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp54822h"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00267-8"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.977"},{"key":"e_1_2_2_19_2","unstructured":"The ATP\u2010dependent reaction requires the presence of both component proteins of nitrogenase to allow ATP\u2010dependent electron transfer from component\u20052 (the reductase component) to the cofactor site of component\u20051 (the catalytic component) for substrate reduction."},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1213159109"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201406863"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201406863"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01809852"},{"key":"e_1_2_2_23_2","unstructured":"A typical Fischer\u2013Tropsch reaction converts a mixture of CO and H2into liquid hydrocarbons."},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1019071117449"}],"container-title":["Angewandte Chemie International 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