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This represents the first occurrence of this very dense network structure outside of SiO<jats:sub>2<\/jats:sub>. Phase\u2010pure coesite PON (<jats:italic>coe<\/jats:italic>\u2010PON) can be synthesized in bulk at pressures above 15\u2005GPa. This compound was thoroughly characterized by means of powder X\u2010ray diffraction, DFT calculations, and FTIR and MAS NMR spectroscopy, as well as temperature\u2010dependent diffraction. These results represent a major step towards the exploration of the phase diagram of PON at very high pressures and the possibly synthesis of a stishovite\u2010type PON containing hexacoordinate phosphorus.<\/jats:p>","DOI":"10.1002\/anie.201410526","type":"journal-article","created":{"date-parts":[[2015,2,9]],"date-time":"2015-02-09T12:54:53Z","timestamp":1423486493000},"page":"4388-4391","source":"Crossref","is-referenced-by-count":20,"title":["A High\u2010Pressure Polymorph of Phosphorus Oxonitride with the Coesite Structure"],"prefix":"10.1002","volume":"54","author":[{"given":"Dominik","family":"Baumann","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Robin","family":"Niklaus","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,2,9]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.7.118"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.2307\/20026061"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.46.1"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.243.4889.367"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2541(94)00140-4"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/0012-821X(95)00123-T"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.118.3057.131"},{"key":"e_1_2_2_8_2","first-page":"975","volume":"40","author":"Ramsdell L. 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