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This novel, general, one\u2010step synthetic procedure uses ferrocene to generate aryl radical species from aryldiazonium salts and allows the straightforward synthesis of brightly fluorescent (<jats:italic>\u03a6<\/jats:italic>&gt;0.85) 3,5\u2010diarylated and 3\u2010monoarylated boron dipyrrins in up to 86\u2009% yield for a broad range of aryl substituents. In this way, new and complex dyes with red\u2010shifted spectra can be easily prepared.<\/jats:p>","DOI":"10.1002\/anie.201410853","type":"journal-article","created":{"date-parts":[[2015,2,16]],"date-time":"2015-02-16T20:27:09Z","timestamp":1424118429000},"page":"4612-4616","source":"Crossref","is-referenced-by-count":137,"title":["Radical C\uf8ffH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red\u2010Shifted 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