{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:28:54Z","timestamp":1786976934533,"version":"build-2736575974"},"reference-count":84,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2015,3,3]],"date-time":"2015-03-03T00:00:00Z","timestamp":1425340800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,4,20]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A novel method for the preparation of functionalized alternating copolymers is presented. Nitroxide\u2010mediated polymerization of hexafluoroisopropyl acrylate with 7\u2010octenyl vinyl ether provides the corresponding alternating polymer, which can be chemically modified using two orthogonal polymer\u2010analogous reactions. A thiol\u2013ene click reaction followed by amidation provides dual\u2010functionalized alternating copolymers. The potential of this method is illustrated by the preparation of a small library (15\u2005examples) of functionalized alternating copolymers.<\/jats:p>","DOI":"10.1002\/anie.201412206","type":"journal-article","created":{"date-parts":[[2015,3,3]],"date-time":"2015-03-03T15:15:23Z","timestamp":1425395723000},"page":"5054-5059","source":"Crossref","is-referenced-by-count":71,"title":["Alternating Copolymerization by Nitroxide\u2010Mediated Polymerization and Subsequent Orthogonal Functionalization"],"prefix":"10.1002","volume":"54","author":[{"given":"Matthias","family":"Tesch","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johannes A. M.","family":"Hepperle","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Henning","family":"Klaasen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Letzel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armido","family":"Studer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,3,3]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b806413j"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.530"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b9py00329k"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1175"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1238149"},{"key":"e_1_2_2_7_2","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0717616"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9031314"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002721"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201002721"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103007"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201103007"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja205080u"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209052"},{"key":"e_1_2_2_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209052"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC45994B"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma4020092"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201300228"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308960"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308960"},{"key":"e_1_2_2_18_2","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990119u"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr940534g"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10567"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/b307652k"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.20033"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.200800720"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002547"},{"key":"e_1_2_2_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201002547"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1080\/15583724.2011.566405"},{"key":"e_1_2_2_27_2","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma991721p"},{"key":"e_1_2_2_29_2","first-page":"232","volume":"32","author":"Chen G.\u2010Q.","year":"1999","journal-title":"Macromolecules"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-3861(03)00397-5"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26956"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4PY01247J"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma011986f"},{"key":"e_1_2_2_34_2","unstructured":"\u00a0"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201100089"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26004"},{"key":"e_1_2_2_37_2","unstructured":"For recent examples see:"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201200036"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma301639m"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26333"},{"key":"e_1_2_2_41_2","unstructured":"For recent examples of amidations with active esters see:"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma4001258"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.24152"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2py20162c"},{"key":"e_1_2_2_45_2","unstructured":"For reviews 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Therefore for larger polymers the dead NBVE\u2010terminated chains are enriched in the MS\u2010visible low\u2010molecular region."},{"key":"e_1_2_2_69_2","unstructured":"In some cases when the polymerization was run without or with less benzene as the solvent we observed gelation after 15\u201330\u2005minutes and the material obtained was hardly soluble in any organic solvent likely because of cross\u2010linking. We attribute this cross\u2010linking behavior to the participation of the terminal alkene which can undergo intramolecular radical cyclization at the chain end as well as chain transfer to the monomer. However when the reaction was run in an adequate amount of benzene we did not find any indication for the participation of the terminal alkene in the polymerization."},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma500304f"},{"key":"e_1_2_2_71_2","unstructured":"HFIP as an additive is known to affect the selectivity of acrylate polymerization and to enhance the alternating polymerization of \u03b1\u2010olefins and acrylates; see:"},{"key":"e_1_2_2_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0518(19990715)37:14<2677::AID-POLA43>3.0.CO;2-F"},{"key":"e_1_2_2_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0518(200012)38:1 <4693::AID-POLA90>3.0.CO;2-7"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma9001275"},{"key":"e_1_2_2_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma300325r"},{"key":"e_1_2_2_76_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma301570r"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201412206","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201412206","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T08:13:36Z","timestamp":1697444016000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201412206"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,3,3]]},"references-count":84,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2015,4,20]]}},"alternative-id":["10.1002\/anie.201412206"],"URL":"https:\/\/doi.org\/10.1002\/anie.201412206","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,3,3]]}}}