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The reaction likely involves two distinct chemical transformations: reversible silyl\u2010imine formation between HMDS and an aldehyde, followed by oxidation mediated by the oxoammonium salt and desilylation to furnish a nitrile. The spent oxidant can be easily recovered and used to regenerate the oxoammonium salt oxidant.<\/jats:p>","DOI":"10.1002\/anie.201412256","type":"journal-article","created":{"date-parts":[[2015,2,9]],"date-time":"2015-02-09T13:02:19Z","timestamp":1423486939000},"page":"4241-4245","source":"Crossref","is-referenced-by-count":118,"title":["Access to Nitriles from Aldehydes Mediated by an Oxoammonium Salt"],"prefix":"10.1002","volume":"54","author":[{"given":"Christopher B.","family":"Kelly","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyle M.","family":"Lambert","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael A.","family":"Mercadante","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John M.","family":"Ovian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William F.","family":"Bailey","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicholas E.","family":"Leadbeater","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,2,9]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60132a001"},{"key":"e_1_2_2_3_2","first-page":"819","volume-title":"Comprehensive Organic Transformations","author":"Larock R. 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