{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T19:43:39Z","timestamp":1791402219482,"version":"4.3.3"},"reference-count":184,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2015,4,2]],"date-time":"2015-04-02T00:00:00Z","timestamp":1427932800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,5,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A palladium\u2010catalyzed enantioselective C\uf8ffH arylation of\n                    <jats:italic>N<\/jats:italic>\n                    \u2010(\n                    <jats:italic>o<\/jats:italic>\n                    \u2010bromoaryl)\u2010diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P\u2010stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P\u2010chiral biphenyl monophosphine ligands.\n                  <\/jats:p>","DOI":"10.1002\/anie.201500201","type":"journal-article","created":{"date-parts":[[2015,4,2]],"date-time":"2015-04-02T18:25:31Z","timestamp":1427999131000},"page":"6265-6269","source":"Crossref","is-referenced-by-count":216,"title":["Palladium\u2010Catalyzed Enantioselective C\uf8ffH Arylation for the Synthesis of P\u2010Stereogenic Compounds"],"prefix":"10.1002","volume":"54","author":[{"given":"Zi\u2010Qi","family":"Lin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei\u2010Zhen","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shao\u2010Bai","family":"Yan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei\u2010Liang","family":"Duan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,4,2]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","volume-title":"Phosphorus Heterocycles II (Topics in Heterocyclic Chemistry Vol.\u200521","year":"2010"},{"key":"e_1_2_3_3_2","volume-title":"Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications, Vols.\u20051\u20133","year":"2008"},{"key":"e_1_2_3_4_2","volume-title":"Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences","year":"2011"},{"key":"e_1_2_3_5_2","unstructured":"For reviews on the synthesis of P\u2010chiral phosphines see:"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a009"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.05.009"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2012.01.007"},{"key":"e_1_2_3_9_2","unstructured":"For selected examples of P\u2010chiral ligands in catalysis see:"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196809422"},{"key":"e_1_2_3_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19680802413"},{"key":"e_1_2_3_11_2","first-page":"1445","author":"Knowles W. 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see:"},{"key":"e_1_2_3_139_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)89366-2"},{"key":"e_1_2_3_140_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol025563p"},{"key":"e_1_2_3_141_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2003.09.109"},{"key":"e_1_2_3_142_2","unstructured":"\u00a0"},{"key":"e_1_2_3_143_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja100606v"},{"key":"e_1_2_3_144_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13785a"},{"key":"e_1_2_3_145_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol2024339"},{"key":"e_1_2_3_146_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201200133"},{"key":"e_1_2_3_147_2","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201300021"},{"key":"e_1_2_3_148_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol402351c"},{"key":"e_1_2_3_149_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC46290K"},{"key":"e_1_2_3_150_2","unstructured":"For X\u2010ray crystal data see the Supporting Information for details."},{"key":"e_1_2_3_151_2","unstructured":"Two atropisomers exist in equilibrium with each other at ambient temperature (25\u2009\u00b0C)."},{"key":"e_1_2_3_152_2","unstructured":"For examples of reduction reactions of chiral phosphine oxides to trivalent phosphines see Ref.\u2005[2] and the following literature:"},{"key":"e_1_2_3_153_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0068041"},{"key":"e_1_2_3_154_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CC14856G"}],"container-title":["Angewandte Chemie International 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