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Realizing a colloidal analogue of a molecular dynamic inclusion complex is challenging because inorganic nanoparticles (NPs) with a well\u2010defined cavity and portal are difficult to synthesize in high yield and with good structural fidelity. Herein, a generic strategy towards the fabrication of dynamic 1:1 inclusion complexes of metal nanoparticles inside oxide nanocups with high yield (&gt;70\u2009%) and regiospecificity (&gt;90\u2009%) by means of a reactive double Janus nanoparticle intermediate is reported. Experimental evidence confirms that the inclusion complexes are formed by a kinetically controlled mechanism involving a delicate interplay between bipolar galvanic corrosion and alloying\u2013dealloying oxidation. Release of the NP guest from the nanocups can be efficiently triggered by an external stimulus.<\/jats:p>","DOI":"10.1002\/anie.201500635","type":"journal-article","created":{"date-parts":[[2015,5,8]],"date-time":"2015-05-08T19:27:33Z","timestamp":1431113253000},"page":"6730-6734","source":"Crossref","is-referenced-by-count":15,"title":["Dynamic Inclusion Complexes of Metal Nanoparticles Inside Nanocups"],"prefix":"10.1002","volume":"54","author":[{"given":"Mariana","family":"Alarc\u00f3n\u2010Correa","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tung\u2010Chun","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peer","family":"Fischer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,5,8]]},"reference":[{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/b902462j"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301665"},{"key":"e_1_2_3_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301665"},{"key":"e_1_2_3_3_2","unstructured":"\u00a0"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020503)41:9<1488::AID-ANIE1488>3.0.CO;2-G"},{"key":"e_1_2_3_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020503)114:9<1556::AID-ANGE1556>3.0.CO;2-C"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/bm201588m"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202947"},{"key":"e_1_2_3_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202947"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201101882"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106394k"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007859"},{"key":"e_1_2_3_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201007859"},{"key":"e_1_2_3_11_2","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200906130"},{"key":"e_1_2_3_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200906130"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0nr00385a"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/14\/10\/314"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/la204395d"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1116\/1.2764082"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3685"},{"key":"e_1_2_3_18_2","unstructured":"http:\/\/www.sigmaaldrich.com\/catalog\/product\/aldrich\/742015?lang=de&region=DE."},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2082735"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1212822"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja039734c"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13658e"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201500635","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201500635","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T16:46:37Z","timestamp":1697474797000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201500635"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,5,8]]},"references-count":27,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2015,6]]}},"alternative-id":["10.1002\/anie.201500635"],"URL":"https:\/\/doi.org\/10.1002\/anie.201500635","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,5,8]]}}}