{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:55:33Z","timestamp":1782885333574,"version":"3.54.5"},"reference-count":38,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2015,4,27]],"date-time":"2015-04-27T00:00:00Z","timestamp":1430092800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,5,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>To date, the access to the substance class of borates containing nitrogen, for example, nitridoborates, oxonitridoborates, or amine borates, was an extreme effort owing to the difficult starting materials and reaction conditions. Although a number of compounds containing boron and nitrogen are known, no adduct of ammonia to an inorganic borate has been observed so far. A new synthetic approach starting from the simple educts CdO, B<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, and aqueous ammonia under conditions of 4.7\u2005GPa and 800\u2009\u00b0C led to the synthesis of Cd(NH<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>[B<jats:sub>3<\/jats:sub>O<jats:sub>5<\/jats:sub>(NH<jats:sub>3<\/jats:sub>)]<jats:sub>2<\/jats:sub> as the first ammine borate. We thoroughly characterized this compound on the basis of low\u2010temperature single\u2010crystal and powder X\u2010ray diffraction data, IR and Raman spectroscopy, and by quantum theoretical calculations. This contribution shows that the adduct of NH<jats:sub>3<\/jats:sub> to the BO<jats:sub>3<\/jats:sub> group of a complex B\u2013O network can be stabilized, opening up a fundamentally new synthetic route to nitrogen\u2010containing borates.<\/jats:p>","DOI":"10.1002\/anie.201500706","type":"journal-article","created":{"date-parts":[[2015,4,27]],"date-time":"2015-04-27T08:59:03Z","timestamp":1430125143000},"page":"6360-6363","source":"Crossref","is-referenced-by-count":38,"title":["High\u2010Pressure Synthesis of Cd(NH<sub>3<\/sub>)<sub>2<\/sub>[B<sub>3<\/sub>O<sub>5<\/sub>(NH<sub>3<\/sub>)]<sub>2<\/sub>: Pioneering the Way to the Substance Class of Ammine Borates"],"prefix":"10.1002","volume":"54","author":[{"given":"Gerhard","family":"Sohr","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nina","family":"Ciaghi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Schauperl","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus","family":"Wurst","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus R.","family":"Liedl","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hubert","family":"Huppertz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,4,27]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja017691z"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703399"},{"key":"e_1_2_2_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703399"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-50775-2_5"},{"key":"e_1_2_2_5_2","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1515\/9783110891577"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9825332"},{"key":"e_1_2_2_8_2","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(99)00053-4"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2013.08.022"},{"key":"e_1_2_2_11_2","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1524\/ncrs.1998.213.14.201","volume":"213","author":"Meyer C.","year":"1998","journal-title":"Z. Kristallogr. New Cryst. Struct."},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200208)628:8<1799::AID-ZAAC1799>3.0.CO;2-L"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201400312"},{"key":"e_1_2_2_14_2","unstructured":"Crystal data for Cd(NH3)2[B3O5(NH3)]2: crystal size: 0.02\u00d70.03\u00d70.03\u2005mm3 space groupFdd2 (no. 43) a=972.33(3) b=2357.95(6) c=883.19(2)\u2005pm V=2.02489(9)\u2005nm3 Z=8 \u03c1calcd: 2.660\u2005g\u2009cm\u22123 Bruker D8 Quest Kappa Mo\u2010K\u03b1\u2010radiation (71.073\u2005pm) multi\u2010scan absorption correction 14408 reflections 2717 independent reflections Rint=0.0369 least\u2010squares refinement onF2 R\u2010values (all data\/I\u22652\u03c3(I)):R1=0.0205\/0.0172 wR2=0.0380\/0.0369 GooF=1.122 for 2549 reflections (I\u22652\u03c3(I)) and 120 parameters Flack\u2010parameter: \u22120.00(2). Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe 76344 Eggenstein\u2010Leopoldshafen Germany (fax: (+49) 7247\u2013808\u2013666; e\u2010mail: crysdata@fiz\u2010karlsruhe.de http:\/\/www.fiz\u2010karlsruhe.de\/request_for_deposited_data.html) on quoting the depository number CSD\u2010429059."},{"key":"e_1_2_2_15_2","unstructured":"\u00a0"},{"key":"e_1_2_2_16_2","unstructured":"The term \u201cdreier\u201d ring was initially coined by F. Liebau in his bookStructural Chemistry of Silicates(Springer\u2010Verlag Berlin (Germany) 1985). It is derived from the German word \u201cdrei\u201d which means three. However a \u201cdreier\u201d ring is not a three\u2010membered ring but a six\u2010membered ring comprising three tetrahedral centers (B). Similar terms exist for rings made up of two four five and six tetrahedral centers namely \u201czweier\u201d \u201cvierer \u201d \u201cf\u00fcnfer \u201d and \u201csechser \u201d rings respectively;"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-50076-3"},{"key":"e_1_2_2_18_2","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","first-page":"1131","volume":"33","author":"Burns P. C.","year":"1995","journal-title":"Can. Mineral."},{"key":"e_1_2_2_20_2","first-page":"731","volume":"37","author":"Grice J. D.","year":"1999","journal-title":"Can. 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