{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,26]],"date-time":"2026-02-26T03:17:31Z","timestamp":1772075851159,"version":"3.50.1"},"reference-count":75,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2015,4,17]],"date-time":"2015-04-17T00:00:00Z","timestamp":1429228800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The reaction of [ClP(\u03bc\u2010PMes*)]<jats:sub>2<\/jats:sub> (<jats:bold>1<\/jats:bold>) with the Lewis acid GaCl<jats:sub>3<\/jats:sub> yielded a hitherto unknown tetraphosphabicyclo[1.1.0]butan\u20102\u2010ium salt, [Mes*P<jats:sub>4<\/jats:sub>(Cl)Mes*][GaCl<jats:sub>4<\/jats:sub>] (<jats:bold>3<\/jats:bold>[GaCl<jats:sub>4<\/jats:sub>]), which incorporates a positively charged phosphonium center within its bicyclic P<jats:sub>4<\/jats:sub> scaffold. The formation of the title compound was studied by means of low\u2010temperature NMR experiments. This led to the identification of an intermediate cyclotetraphosphenium cation, which was trapped by reaction with dimethylbutadiene (dmb). All of the compounds were fully characterized by experimental and computational methods.<\/jats:p>","DOI":"10.1002\/anie.201500892","type":"journal-article","created":{"date-parts":[[2015,4,17]],"date-time":"2015-04-17T22:28:53Z","timestamp":1429309733000},"page":"6926-6930","source":"Crossref","is-referenced-by-count":38,"title":["Low\u2010Temperature Isolation of the Bicyclic Phosphinophosphonium Salt [Mes*<sub>2<\/sub>P<sub>4<\/sub>Cl][GaCl<sub>4<\/sub>]"],"prefix":"10.1002","volume":"54","author":[{"given":"Jonas","family":"Bresien","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kirill","family":"Faust","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,4,17]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00312-X"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/B514861H"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400547x"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja027946o"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic050770h"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704367"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704367"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11224-010-9653-3"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302725"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302725"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b517459g"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201100663"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201100663"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19931260703"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710853b"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801674"},{"key":"e_1_2_2_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801674"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic900821h"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203267"},{"key":"e_1_2_2_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203267"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200501850"},{"key":"e_1_2_2_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200501850"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0622499"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja907693f"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102150s"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902369"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201414"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201201414"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20011203)40:23<4406::AID-ANIE4406>3.0.CO;2-X"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20011203)113:23<4544::AID-ANGE4544>3.0.CO;2-C"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201262"},{"key":"e_1_2_2_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201201262"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906878q"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302914"},{"key":"e_1_2_2_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302914"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201109010"},{"key":"e_1_2_2_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201109010"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403631"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-2002-0909"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic8016003"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703055"},{"key":"e_1_2_2_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703055"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201405879"},{"key":"e_1_2_2_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201405879"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201403295"},{"key":"e_1_2_2_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201403295"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00020a010"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher",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