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X\u2010ray structure determination of (<jats:italic>E<\/jats:italic>)\u20101,2\u2010bis{(<jats:italic>E<\/jats:italic>)\u20102\u2010chloro\u20101\u2010(chloroimino)\u20102,2\u2010dinitroethyl}diazene) (<jats:bold>10<\/jats:bold>), N1, N2\u2010dichloro\u20101, 2\u2010diazenedicarboximidamide (<jats:bold>11<\/jats:bold>), and (<jats:italic>E<\/jats:italic>,<jats:italic>E<\/jats:italic>)\u2010<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032\u20101,2\u2010ethanediylidenebis(2, 2\u2010dinitro\u20102\u2010chloro\u2010ethanamine) (<jats:bold>12<\/jats:bold>) was helpful in their characterization. Heats of formation (HOF) were calculated (Gaussian\u200903) and combined with experimental densities to estimate the detonation velocities (<jats:italic>D<\/jats:italic>) and pressures (<jats:italic>P<\/jats:italic>) of the high\u2010energy\u2010density materials (HEDMs) (EXPLO5, v6.01). The compounds exhibit good thermal stability, high density, positive HOF, acceptable oxygen balances, and excellent detonation properties, which often are superior to that of 1,3,5\u2010trinitroperhydro\u20101,3,5\u2010triazine (RDX).<\/jats:p>","DOI":"10.1002\/anie.201501973","type":"journal-article","created":{"date-parts":[[2015,3,30]],"date-time":"2015-03-30T23:05:32Z","timestamp":1427756732000},"page":"6335-6338","source":"Crossref","is-referenced-by-count":84,"title":["The Many Faces of FOX\u20107: A Precursor to High\u2010Performance Energetic Materials"],"prefix":"10.1002","volume":"54","author":[{"given":"Haixiang","family":"Gao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean'ne M.","family":"Shreeve","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,3,30]]},"reference":[{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2008.04.011"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.09.058"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1080\/07370651003749196"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500364t"},{"key":"e_1_2_2_5_2","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00037a015"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00027a042"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/prep.201300123"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(98)00673-5"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/9781847551955-00001"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1080\/07370652.2011.633964"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp508869n"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/prep.200800035"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp010289m"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.4896165"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2008.01.026"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2014.12.006"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1023\/B:RUJO.0000045193.49958.c4"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic202288t"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5074036"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja406629g"},{"key":"e_1_2_2_22_2","unstructured":"\u00a0"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/0471224480"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00075a002"},{"key":"e_1_2_2_25_2","unstructured":"\u00a0"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA03016H"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203493"},{"key":"e_1_2_2_28_2","unstructured":"\u00a0"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102136r"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja103935q"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002858"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.05.010"},{"key":"e_1_2_2_33_2","unstructured":"A. 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