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The resulting phosphine antimony(I) complexes catenate to give the first examples of cationic antimony bicyclic compounds, [(R<jats:sub>3<\/jats:sub>P)<jats:sub>4<\/jats:sub>Sb<jats:sub>6<\/jats:sub>]<jats:sup>4+<\/jats:sup>, featuring a bicyclo[3.1.0]hexastibine framework stabilized by four phosphine ligands. The unprecedented 14\u2010electron redox process illustrates the generality of the reductive catenation method.<\/jats:p>","DOI":"10.1002\/anie.201503074","type":"journal-article","created":{"date-parts":[[2015,6,4]],"date-time":"2015-06-04T02:52:43Z","timestamp":1433386363000},"page":"7828-7832","source":"Crossref","is-referenced-by-count":25,"title":["Reductive Catenation of Phosphine Antimony Complexes"],"prefix":"10.1002","volume":"54","author":[{"given":"Saurabh S.","family":"Chitnis","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Neil","family":"Burford","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jan J.","family":"Weigand","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Robert","family":"McDonald","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,6,3]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(97)00012-X"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527602445.ch2c"},{"key":"e_1_2_3_4_2","doi-asserted-by":"crossref","first-page":"188","DOI":"10.1002\/3527602445.ch2e","volume-title":"Molecular Clusters of the Main Group Elements","author":"Wiberg N.","year":"2004"},{"key":"e_1_2_3_5_2","doi-asserted-by":"crossref","DOI":"10.1039\/9781849730471","volume-title":"Inorganic Rings and Polymers of the p\u2010Block Elements","author":"Chivers T.","year":"2009"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001630"},{"key":"e_1_2_3_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001630"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00321-6"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400547x"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.10.010"},{"key":"e_1_2_3_10_2","unstructured":"For Se and Te see:"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00230-7"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.06.011"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/om800912v"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050938y"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja002344v"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.275.5296.60"},{"key":"e_1_2_3_17_2","unstructured":"\u00a0"},{"key":"e_1_2_3_18_2","first-page":"1259","volume":"89","author":"Miller R. 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