{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T22:30:05Z","timestamp":1792017005366,"version":"4.4.0"},"reference-count":107,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2015,6,18]],"date-time":"2015-06-18T00:00:00Z","timestamp":1434585600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,8,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A novel method for convenient access to CF<jats:sub>3<\/jats:sub>\u2010containing azirines has been developed, and involves a copper\u2010catalyzed trifluoromethylazidation of alkynes and a photocatalyzed rearrangement. Both terminal and internal alkynes are compatible with the mild reaction conditions, thus delivering the CF<jats:sub>3<\/jats:sub>\u2010containing azirines in moderate to good yields. The azirines can be converted into various CF<jats:sub>3<\/jats:sub>\u2010substituted aziridines.<\/jats:p>","DOI":"10.1002\/anie.201503412","type":"journal-article","created":{"date-parts":[[2015,6,18]],"date-time":"2015-06-18T20:33:39Z","timestamp":1434659619000},"page":"9356-9360","source":"Crossref","is-referenced-by-count":154,"title":["Copper\u2010Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF<sub>3<\/sub>\u2010Substituted Azirines and Aziridines"],"prefix":"10.1002","volume":"54","author":[{"given":"Fei","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pinhong","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinxing","family":"Ye","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guosheng","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,6,18]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/B978-008096519-2.00110-7","volume-title":"Comprehensive Heterocyclic Chemistry, Vol.\u20057","author":"Padwa A.","year":"1984"},{"key":"e_1_2_2_3_2","first-page":"45","volume-title":"Advance in Heterocyclic Chemistry","author":"Fowler F. W.","year":"1971"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400543u"},{"key":"e_1_2_2_5_2","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr078199m"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00117a050"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo702435s"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00044-010-9437-8"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1139\/v96-178"},{"key":"e_1_2_2_11_2","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1080\/00304940209356770"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400553c"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400582d"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500064w"},{"key":"e_1_2_2_16_2","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-662-04164-2"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781444312096"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)81291-6"},{"key":"e_1_2_2_22_2","unstructured":"\u00a0"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19324930119"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050586v"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400602"},{"key":"e_1_2_2_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400602"},{"key":"e_1_2_2_26_2","unstructured":"\u00a0"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01096a045"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00967a033"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199001031"},{"key":"e_1_2_2_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19901020126"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(03)01205-X"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc31426f"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.9.201"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol501661k"},{"key":"e_1_2_2_34_2","unstructured":"\u00a0"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar7002573"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr800388c"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja409941r"},{"key":"e_1_2_2_38_2","unstructured":"For some reviews on trifluoromethylation see:"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600449"},{"key":"e_1_2_2_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600449"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr800221v"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr1004293"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202624"},{"key":"e_1_2_2_42_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202624"},{"key":"e_1_2_2_43_2","first-page":"2919","author":"Chen P.","year":"2013","journal-title":"Synthesis"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309260"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201309260"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500223h"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400473a"},{"key":"e_1_2_2_47_2","unstructured":"\u00a0"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201104053"},{"key":"e_1_2_2_48_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201104053"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja206330m"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja207775a"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja210614y"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol3011419"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201095"},{"key":"e_1_2_2_53_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201201095"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305840g"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202623"},{"key":"e_1_2_2_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202623"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205071"},{"key":"e_1_2_2_56_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201205071"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja403954g"},{"key":"e_1_2_2_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201210250"},{"key":"e_1_2_2_58_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201210250"},{"key":"e_1_2_2_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201303350"},{"key":"e_1_2_2_59_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201303350"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302673"},{"key":"e_1_2_2_60_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302673"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304557"},{"key":"e_1_2_2_61_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304557"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja401022x"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc43936d"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307377"},{"key":"e_1_2_2_64_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307377"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo401831t"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol403263c"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol403391v"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo5012619"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol501574f"},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol500374e"},{"key":"e_1_2_2_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol5021477"},{"key":"e_1_2_2_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201300433"},{"key":"e_1_2_2_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402511"},{"key":"e_1_2_2_73_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402511"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308735"},{"key":"e_1_2_2_74_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308735"},{"key":"e_1_2_2_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol502071g"},{"key":"e_1_2_2_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201403383"},{"key":"e_1_2_2_76_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201403383"},{"key":"e_1_2_2_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05692B"},{"key":"e_1_2_2_78_2","unstructured":"\u00a0"},{"key":"e_1_2_2_79_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309991"},{"key":"e_1_2_2_79_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201309991"},{"key":"e_1_2_2_80_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja504458j"},{"key":"e_1_2_2_81_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2014.04.004"},{"key":"e_1_2_2_82_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00939"},{"key":"e_1_2_2_83_2","unstructured":"For the precedent transformation from azirine to aziridines see:"},{"key":"e_1_2_2_84_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2005.12.119"},{"key":"e_1_2_2_85_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2014.01.037"},{"key":"e_1_2_2_86_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2011.08.006"},{"key":"e_1_2_2_87_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol802120u"},{"key":"e_1_2_2_88_2","unstructured":"For the CF3radical generation from the mutually activated CF3+reagent2\u2009awith silyl reagent see Ref.\u2005[12a]."},{"key":"e_1_2_2_89_2","doi-asserted-by":"publisher","DOI":"10.1039\/p29890000689"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201503412","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201503412","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T05:31:05Z","timestamp":1697434265000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201503412"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,6,18]]},"references-count":107,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2015,8,3]]}},"alternative-id":["10.1002\/anie.201503412"],"URL":"https:\/\/doi.org\/10.1002\/anie.201503412","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,6,18]]}}}