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Herein we report the rational design of novel V\u2010shaped barbiturate (Ba) functionalized soft\u2013hard\u2013soft triblock copolymers with a reversible supramolecular healing motif (Ba) in the central part of the hard block, which undergoes autonomic repair at 30\u2009\u00b0C. The designed synthesis also offers a suitable macromolecular building block to further self\u2010assemble with heterocomplementary \u03b1,\u03c9\u2010Hamilton wedge (HW) functionalized polyisoprene (PI; HW\u2010PI\u2010HW), resulting in an H\u2010shaped supramolecular architecture with efficient self\u2010healing capabilities that can recover up to around 95\u2009% of the original mechanical performance at 30\u2009\u00b0C within 24\u2005h.<\/jats:p>","DOI":"10.1002\/anie.201504136","type":"journal-article","created":{"date-parts":[[2015,7,1]],"date-time":"2015-07-01T19:52:32Z","timestamp":1435780352000},"page":"10188-10192","source":"Crossref","is-referenced-by-count":121,"title":["Self\u2010Healing Materials from V\u2010 and H\u2010Shaped Supramolecular Architectures"],"prefix":"10.1002","volume":"54","author":[{"given":"Senbin","family":"Chen","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nasir","family":"Mahmood","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mario","family":"Beiner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wolfgang H.","family":"Binder","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,7]]},"reference":[{"key":"e_1_2_2_1_2","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","volume-title":"Self\u2010Healing Polymers. 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