{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:19:01Z","timestamp":1791263941930,"version":"4.1.0"},"reference-count":126,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2015,7,31]],"date-time":"2015-07-31T00:00:00Z","timestamp":1438300800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"EU FP7 Marie Curie Academic-Industrial Initial Training Network"},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council (EPSRC)","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,9,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The subcomponent self\u2010assembly of a bent dialdehyde ligand and different cationic and anionic templates led to the formation of two new metallosupramolecular architectures: a Fe<jats:sup>II<\/jats:sup><jats:sub>4<\/jats:sub>L<jats:sub>6<\/jats:sub> molecular rectangle was isolated following reaction of the ligand with iron(II) tetrafluoroborate, and a M<jats:sub>5<\/jats:sub>L<jats:sub>6<\/jats:sub> trigonal bipyramidal structure was constructed from either zinc(II) tetrafluoroborate or cadmium(II) trifluoromethanesulfonate. The spatially constrained arrangement of the three equatorial metal ions in the M<jats:sub>5<\/jats:sub>L<jats:sub>6<\/jats:sub> structures was found to induce small\u2010molecule transformations. Atmospheric carbon dioxide was fixed as carbonate and bound to the equatorial metal centers in both the Zn<jats:sub>5<\/jats:sub>L<jats:sub>6<\/jats:sub> and Cd<jats:sub>5<\/jats:sub>L<jats:sub>6<\/jats:sub> assemblies, and sulfur dioxide was hydrated and bound as the sulfite dianion in the Zn<jats:sub>5<\/jats:sub>L<jats:sub>6<\/jats:sub> structure. Subsequent in situ oxidation of the sulfite dianion resulted in a sulfate dianion bound within the supramolecular pocket.<\/jats:p>","DOI":"10.1002\/anie.201504856","type":"journal-article","created":{"date-parts":[[2015,8,1]],"date-time":"2015-08-01T10:27:14Z","timestamp":1438424834000},"page":"11122-11127","source":"Crossref","is-referenced-by-count":33,"title":["Carbon Dioxide Fixation and Sulfate Sequestration by a Supramolecular Trigonal Bipyramid"],"prefix":"10.1002","volume":"54","author":[{"given":"Colm","family":"Browne","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William J.","family":"Ramsay","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tanya K.","family":"Ronson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John","family":"Medley\u2010Hallam","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan R.","family":"Nitschke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,7,31]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"T.\u2005R. Cook P.\u2005J. Stang Chem. Rev.\u00ad2015 DOI:."},{"key":"e_1_2_3_2_2","unstructured":"\u00a0"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500875"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527645787.ch2"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/B821019P"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527625468.ch23"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805340"},{"key":"e_1_2_3_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805340"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.05.016"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800796"},{"key":"e_1_2_3_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800796"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1407"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3082473"},{"key":"e_1_2_3_13_2","unstructured":"\u00a0"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200077m"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar040152p"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/b906726b"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/b926229f"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1070821"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc36363a"},{"key":"e_1_2_3_20_2","unstructured":"\u00a0"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja202055v"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja412582k"},{"key":"e_1_2_3_23_2","unstructured":"\u00a0"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400285"},{"key":"e_1_2_3_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400285"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2156"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC02573A"},{"key":"e_1_2_3_27_2","unstructured":"\u00a0"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja309031h"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/29501"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1063789"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja803341y"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300677w"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob27481k"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705346"},{"key":"e_1_2_3_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200705346"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902717"},{"key":"e_1_2_3_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902717"},{"key":"e_1_2_3_36_2","unstructured":"\u00a0"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209382"},{"key":"e_1_2_3_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209382"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1408"},{"key":"e_1_2_3_39_2","unstructured":"\u00a0"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188605"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303181"},{"key":"e_1_2_3_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902993"},{"key":"e_1_2_3_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201407144"},{"key":"e_1_2_3_43_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201407144"},{"key":"e_1_2_3_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10263j"},{"key":"e_1_2_3_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja511463k"},{"key":"e_1_2_3_46_2","unstructured":"\u00a0"},{"key":"e_1_2_3_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199003111"},{"key":"e_1_2_3_47_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19901020309"},{"key":"e_1_2_3_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020118)8:2<493::AID-CHEM493>3.0.CO;2-5"},{"key":"e_1_2_3_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar970224v"},{"key":"e_1_2_3_50_2","unstructured":"\u00a0"},{"key":"e_1_2_3_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208740"},{"key":"e_1_2_3_51_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201208740"},{"key":"e_1_2_3_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501081"},{"key":"e_1_2_3_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503095"},{"key":"e_1_2_3_53_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503095"},{"key":"e_1_2_3_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja001991j"},{"key":"e_1_2_3_55_2","unstructured":"\u00a0"},{"key":"e_1_2_3_56_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1096914"},{"key":"e_1_2_3_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404270"},{"key":"e_1_2_3_57_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404270"},{"key":"e_1_2_3_58_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2056"},{"key":"e_1_2_3_59_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2205"},{"key":"e_1_2_3_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702075"},{"key":"e_1_2_3_60_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200702075"},{"key":"e_1_2_3_61_2","unstructured":"\u00a0"},{"key":"e_1_2_3_62_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature09963"},{"key":"e_1_2_3_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/mz300224x"},{"key":"e_1_2_3_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja504748g"},{"key":"e_1_2_3_65_2","unstructured":"\u00a0"},{"key":"e_1_2_3_66_2","doi-asserted-by":"publisher","DOI":"10.1039\/B808264M"},{"key":"e_1_2_3_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/b806041j"},{"key":"e_1_2_3_68_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60316D"},{"key":"e_1_2_3_69_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.283"},{"key":"e_1_2_3_70_2","unstructured":"\u00a0"},{"key":"e_1_2_3_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0340884"},{"key":"e_1_2_3_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500786"},{"key":"e_1_2_3_72_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500786"},{"key":"e_1_2_3_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200700265"},{"key":"e_1_2_3_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900606"},{"key":"e_1_2_3_75_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107184"},{"key":"e_1_2_3_75_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107184"},{"key":"e_1_2_3_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400626"},{"key":"e_1_2_3_76_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400626"},{"key":"e_1_2_3_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01597A"},{"key":"e_1_2_3_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja311285b"},{"key":"e_1_2_3_79_2","unstructured":"\u00a0"},{"key":"e_1_2_3_80_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0909049512008801"},{"key":"e_1_2_3_81_2","unstructured":"CCDC\u20051400514 1400515 1400516 1400517contain the supplementary crystallographic data for this paper. These data can be obtained free of charge fromThe Cambridge Crystallographic Data Centre."},{"key":"e_1_2_3_82_2","unstructured":"\u00a0"},{"key":"e_1_2_3_83_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.131048"},{"key":"e_1_2_3_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199311791"},{"key":"e_1_2_3_84_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19931050822"},{"key":"e_1_2_3_85_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803066"},{"key":"e_1_2_3_85_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803066"},{"key":"e_1_2_3_86_2","doi-asserted-by":"publisher","DOI":"10.1039\/a808370c"},{"key":"e_1_2_3_87_2","doi-asserted-by":"publisher","DOI":"10.1080\/10610278.2012.688127"},{"key":"e_1_2_3_88_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9706626"},{"key":"e_1_2_3_89_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020715)41:14<2515::AID-ANIE2515>3.0.CO;2-Q"},{"key":"e_1_2_3_89_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020715)114:14<2625::AID-ANGE2625>3.0.CO;2-K"},{"key":"e_1_2_3_90_2","unstructured":"\u00a0"},{"key":"e_1_2_3_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja803115j"},{"key":"e_1_2_3_92_2","doi-asserted-by":"publisher","DOI":"10.1039\/b608991g"},{"key":"e_1_2_3_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc12055g"},{"key":"e_1_2_3_94_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.012540799"},{"key":"e_1_2_3_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja505414x"},{"key":"e_1_2_3_96_2","unstructured":"\u00a0"},{"key":"e_1_2_3_97_2","doi-asserted-by":"publisher","DOI":"10.1039\/b905061b"},{"key":"e_1_2_3_98_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic202537c"},{"key":"e_1_2_3_99_2","doi-asserted-by":"publisher","DOI":"10.1039\/b913946j"},{"key":"e_1_2_3_100_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206990"},{"key":"e_1_2_3_100_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206990"},{"key":"e_1_2_3_101_2","doi-asserted-by":"publisher","DOI":"10.1039\/a603049a"},{"key":"e_1_2_3_102_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1981.156.3-4.233"},{"key":"e_1_2_3_103_2","unstructured":"\u00a0"},{"key":"e_1_2_3_104_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic2020379"},{"key":"e_1_2_3_105_2","doi-asserted-by":"publisher","DOI":"10.1039\/b610938a"},{"key":"e_1_2_3_106_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2003.09.148"},{"key":"e_1_2_3_107_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2509(81)80124-8"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201504856","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201504856","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T16:10:27Z","timestamp":1697472627000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201504856"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,7,31]]},"references-count":126,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2015,9,14]]}},"alternative-id":["10.1002\/anie.201504856"],"URL":"https:\/\/doi.org\/10.1002\/anie.201504856","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,7,31]]}}}