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S. Department of Energy, Office of Science, Office of Basic Energy Sciences","award":["DE-AC02-06CH11357"],"award-info":[{"award-number":["DE-AC02-06CH11357"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,11,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Two mesoporous fluorinated metal\u2013organic frameworks (MOFs) were synthesized from extensively fluorinated tritopic carboxylate\u2010 and tetrazolate\u2010based ligands. The tetrazolate\u2010based framework MOFF\u20105 has an accessible surface area of 2445\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>, the highest among fluorinated MOFs. Crystals of MOFF\u20105 adsorb hydrocarbons, fluorocarbons, and chlorofluorocarbons (CFCs)\u2014the latter two being ozone\u2010depleting substances and potent greenhouse species\u2014with weight capacities of up to 225\u2009%. The material exhibits an apparent preference for the adsorption of non\u2010spherical molecules, binding unusually low amounts of both tetrafluoromethane and sulfur hexafluoride.<\/jats:p>","DOI":"10.1002\/anie.201505149","type":"journal-article","created":{"date-parts":[[2015,10,1]],"date-time":"2015-10-01T12:29:20Z","timestamp":1443702560000},"page":"13902-13906","source":"Crossref","is-referenced-by-count":129,"title":["Mesoporous Fluorinated Metal\u2013Organic Frameworks with Exceptional Adsorption of Fluorocarbons and CFCs"],"prefix":"10.1002","volume":"54","author":[{"given":"Teng\u2010Hao","family":"Chen","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ilya","family":"Popov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Watchareeya","family":"Kaveevivitchai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Chun","family":"Chuang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Sheng","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Allan J.","family":"Jacobson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ognjen \u0160.","family":"Miljani\u0107","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,10]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"IPCC Fourth Assessment Report Climate Change 2007: Net Global Radiative Forcing Global Warming Potentials and Patterns of Forcing.http:\/\/www.ipcc.ch\/publications_and_data\/ar4\/wg1\/en\/tssts\u20102\u20105.html."},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/352760393X"},{"key":"e_1_2_3_3_2","unstructured":"United Nations Environment Programme Ozone Secretariat.See:http:\/\/ozone.unep.org\/new_site\/en\/montreal_protocol.php."},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/ngeo2109"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja508818j"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja412893c"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6131"},{"key":"e_1_2_3_8_2","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2012.02.021"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5368"},{"key":"e_1_2_3_11_2","unstructured":"For recent examples see:"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature11893"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja400754p"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja208408n"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804739"},{"key":"e_1_2_3_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804739"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0775265"},{"key":"e_1_2_3_17_2","unstructured":"\u00a0"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2047717"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar9000058"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077862l"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja805688p"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc41564c"},{"key":"e_1_2_3_23_2","unstructured":"CCDC1034688 (MOFF\u20104) and 1034689 (MOFF\u20105) contain the supplementary crystallographic data for this paper. 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Approximate size of crystals used was 0.1\u00d70.1\u00d70.05\u2005mm."},{"key":"e_1_2_3_47_2","doi-asserted-by":"publisher","DOI":"10.1007\/s13762-013-0202-7"},{"key":"e_1_2_3_48_2","unstructured":"This amount is approximately three\u2010times greater than that adsorbed within the pores of an extensively fluorinated noncovalent framework reported in Ref.\u2005[7]."},{"key":"e_1_2_3_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp502137j"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201505149","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201505149","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,17]],"date-time":"2023-10-17T04:44:17Z","timestamp":1697517857000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201505149"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,10]]},"references-count":52,"journal-issue":{"issue":"47","published-print":{"date-parts":[[2015,11,16]]}},"alternative-id":["10.1002\/anie.201505149"],"URL":"https:\/\/doi.org\/10.1002\/anie.201505149","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,10]]}}}