{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T12:32:01Z","timestamp":1790512321867,"version":"4.1.0"},"reference-count":87,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T00:00:00Z","timestamp":1440547200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21302200"],"award-info":[{"award-number":["21302200"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,10,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>An unprecedented rhodium(III)\u2010catalyzed regioselective redox\u2010neutral annulation reaction of 1\u2010naphthylamine N\u2010oxides with diazo compounds was developed to afford various biologically important 1<jats:italic>H<\/jats:italic>\u2010benzo[g]indolines. This coupling reaction proceeds under mild reaction conditions and does not require external oxidants. The only by\u2010products are dinitrogen and water. More significantly, this reaction represents the first example of dual functiaonalization of unactivated a primary C(sp<jats:sup>3<\/jats:sup>)\uf8ffH bond and C(sp<jats:sup>2<\/jats:sup>)\uf8ffH bond with diazocarbonyl compounds. DFT calculations revealed that an intermediate iminium is most likely involved in the catalytic cycle. Moreover, a rhodium(III)\u2010catalyzed coupling of readily available tertiary aniline N\u2010oxides with \u03b1\u2010diazomalonates was also developed under external oxidant\u2010free conditions to access various aminomandelic acid derivatives by an O\u2010atom\u2010transfer reaction.<\/jats:p>","DOI":"10.1002\/anie.201505302","type":"journal-article","created":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T13:57:51Z","timestamp":1440597471000},"page":"12121-12126","source":"Crossref","is-referenced-by-count":135,"title":["Redox\u2010Neutral Rhodium\u2010Catalyzed C\uf8ffH Functionalization of Arylamine <i>N<\/i>\u2010Oxides with Diazo Compounds: Primary C(sp<sup>3<\/sup>)\uf8ffH\/C(sp<sup>2<\/sup>)\uf8ffH Activation and Oxygen\u2010Atom Transfer"],"prefix":"10.1002","volume":"54","author":[{"given":"Bing","family":"Zhou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoqiang","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaxi","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen","family":"Ai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huanyu","family":"Tang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunxiang","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiliang","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanchao","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,8,26]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"For recent reviews see:"},{"key":"e_1_2_3_2_2","first-page":"704","volume":"112","author":"Doyle M. 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