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The M\n                    <jats:sup>2+<\/jats:sup>\n                    reacts with the \u03bc\n                    <jats:sub>3<\/jats:sub>\n                    \u2010OH and terminal H\n                    <jats:sub>2<\/jats:sub>\n                    O ligands on an 8\u2010connected [Zr\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (OH)\n                    <jats:sub>8<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>4<\/jats:sub>\n                    ] cluster to form a bimetallic [Zr\n                    <jats:sub>6<\/jats:sub>\n                    M\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>8<\/jats:sub>\n                    (OH)\n                    <jats:sub>8<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>8<\/jats:sub>\n                    ] cluster. Along with the metalation of Zr\n                    <jats:sub>6<\/jats:sub>\n                    cluster, ligand migration is observed in which a Zr\u2013carboxylate bond dissociates to form a M\u2013carboxylate bond. Single\u2010crystal to single\u2010crystal transformation is realized so that snapshots for cooperative cluster metalation and ligand migration processes are captured by successive single\u2010crystal X\u2010ray structures. In\n                    <jats:sup>3+<\/jats:sup>\n                    was metalated into the same Zr\u2010MOF which showed excellent catalytic activity in the acetaldehyde cyclotrimerization reaction. This work not only provides a powerful tool to functionalize Zr\u2010MOFs with other metals, but also structurally elucidates the formation mechanism of the resulting heterometallic MOFs.\n                  <\/jats:p>","DOI":"10.1002\/anie.201505625","type":"journal-article","created":{"date-parts":[[2015,10,24]],"date-time":"2015-10-24T07:37:25Z","timestamp":1445672245000},"page":"14696-14700","source":"Crossref","is-referenced-by-count":185,"title":["Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal\u2013Organic 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