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The MoO<jats:sub>2<\/jats:sub>@PC\u2010RGO hybrid material derived from the POMOFs\/GO composite is prepared at a relatively low carbonization temperature, which presents a superior activity for the hydrogen\u2010evolution reaction (HER) in acidic media owing to the synergistic effects among highly dispersive MoO<jats:sub>2<\/jats:sub> particles, phosphorus\u2010doped porous carbon, and RGO substrates. MoO<jats:sub>2<\/jats:sub>@PC\u2010RGO exhibits a very positive onset potential close to that of 20\u2009% Pt\/C, low Tafel slope of 41\u2005mV\u2009dec<jats:sup>\u22121<\/jats:sup>, high exchange current density of 4.8\u00d710<jats:sup>\u22124<\/jats:sup>\u2005A\u2009cm<jats:sup>\u22122<\/jats:sup>, and remarkable long\u2010term cycle stability. It is one of the best high\u2010performance catalysts among the reported nonprecious metal catalysts for HER to date.<\/jats:p>","DOI":"10.1002\/anie.201505691","type":"journal-article","created":{"date-parts":[[2015,10,5]],"date-time":"2015-10-05T10:37:24Z","timestamp":1444041444000},"page":"12928-12932","source":"Crossref","is-referenced-by-count":399,"title":["Porous Molybdenum\u2010Based Hybrid Catalysts for Highly Efficient Hydrogen 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