{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T02:11:54Z","timestamp":1740103914902,"version":"3.37.3"},"reference-count":58,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2015,11,9]],"date-time":"2015-11-09T00:00:00Z","timestamp":1447027200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2016,1,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The reaction of the phosphinidene complex [Cp*P{W(CO)<jats:sub>5<\/jats:sub>}<jats:sub>2<\/jats:sub>] (<jats:bold>1\u2009a<\/jats:bold>) with di\u2010tert\u2010butylcarboimidophosphene leads to the P\uf8ffC cage compound <jats:bold>6<\/jats:bold> and the Lewis acid\u2013base adduct [Cp*P{W(CO)<jats:sub>5<\/jats:sub>}<jats:sub>2<\/jats:sub>(CNtBu)] (<jats:bold>2\u2009a<\/jats:bold>). In contrast, the arsinidene complex shows a different reactivity. At low temperatures, the arsaphosphene complex [{W(CO)<jats:sub>5<\/jats:sub>}{\u03b7<jats:sup>2<\/jats:sup>\u2010(Cp*)As\uf8feP(tBu)}{W(CO)<jats:sub>5<\/jats:sub>}] (<jats:bold>3<\/jats:bold>) is formed. At these temperatures, <jats:bold>3<\/jats:bold> reacts further with a second equivalent of carboimidophosphene to form [{W(CO)<jats:sub>5<\/jats:sub>}{\u03b7<jats:sup>2<\/jats:sup>\u2010{(Cp*)(tBu)P}As\uf8feP(tBu)}{W(CO)<jats:sub>5<\/jats:sub>}] (<jats:bold>5<\/jats:bold>), probably by the insertion of a phosphinidene unit (tBuP) into an As\uf8ffC bond. In contrast, at room temperature <jats:bold>3<\/jats:bold> reacts further by a radical\u2010type reaction to form [{(tBu)P\uf8feAs\uf8ffAs\uf8feP(tBu)}{W(CO)<jats:sub>5<\/jats:sub>}<jats:sub>4<\/jats:sub>] (<jats:bold>4<\/jats:bold>). Compound <jats:bold>4<\/jats:bold> is the first example of a neutral, 1,3\u2010butadiene analogue containing only mixed heavier Group\u200515 elements. It consists of two P\uf8feAs double bonds connected by arsenic atoms.<\/jats:p>","DOI":"10.1002\/anie.201507355","type":"journal-article","created":{"date-parts":[[2015,11,9]],"date-time":"2015-11-09T09:26:57Z","timestamp":1447061217000},"page":"431-435","source":"Crossref","is-referenced-by-count":11,"title":["Stepwise Formation of a 1,3\u2010Butadiene Analogue of Mixed Heavier Group\u200515 Elements"],"prefix":"10.1002","volume":"55","author":[{"given":"Michael","family":"Seidl","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexey Y.","family":"Timoshkin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,11,9]]},"reference":[{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39810000191"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.214.4527.1343"},{"key":"e_1_2_4_4_2","unstructured":"\u00a0"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9408989"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199725031"},{"key":"e_1_2_4_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971092231"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001016)39:20<3703::AID-ANIE3703>3.0.CO;2-9"},{"key":"e_1_2_4_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001016)112:20<3847::AID-ANGE3847>3.0.CO;2-K"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/om040056s"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200502865"},{"key":"e_1_2_4_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200502865"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic8016003"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc36888a"},{"key":"e_1_2_4_13_2","unstructured":"\u00a0"},{"key":"e_1_2_4_14_2","doi-asserted-by":"publisher","DOI":"10.1070\/MC2003v013n05ABEH001814"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220606"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9801148"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2014.903489"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404653"},{"key":"e_1_2_4_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404653"},{"key":"e_1_2_4_19_2","unstructured":"\u00a0"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19951280617"},{"key":"e_1_2_4_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic402159y"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410191"},{"key":"e_1_2_4_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410191"},{"key":"e_1_2_4_23_2","unstructured":"\u00a0"},{"key":"e_1_2_4_24_2","first-page":"597","author":"Huy N. 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