{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T13:25:08Z","timestamp":1789651508567,"version":"4.0.0"},"reference-count":52,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2015,10,12]],"date-time":"2015-10-12T00:00:00Z","timestamp":1444608000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"National Science Foundation","award":["CHE 1361654"],"award-info":[{"award-number":["CHE 1361654"]}]},{"name":"Materials Research Laboratory"},{"name":"NSF MRSEC","award":["DMR 1121053"],"award-info":[{"award-number":["DMR 1121053"]}]},{"name":"NIH","award":["1S10OD012077-01A1"],"award-info":[{"award-number":["1S10OD012077-01A1"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2015,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The addition of 1\u2005equiv of KSCPh<jats:sub>3<\/jats:sub> to [L<jats:sup>R<\/jats:sup>NiCl] (L<jats:sup>R<\/jats:sup>={(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)NC(R)}<jats:sub>2<\/jats:sub>CH; R=Me, <jats:italic>t<\/jats:italic>Bu) in C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub> results in the formation of [L<jats:sup>R<\/jats:sup>Ni(SCPh<jats:sub>3<\/jats:sub>)] (<jats:bold>1<\/jats:bold>: R=Me; <jats:bold>2<\/jats:bold>: R=<jats:italic>t<\/jats:italic>Bu) in good yields. Subsequent reduction of <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> with 2\u2005equiv of KC<jats:sub>8<\/jats:sub> in cold (\u221225\u2009\u00b0C) Et<jats:sub>2<\/jats:sub>O in the presence of 2\u2005equiv of 18\u2010crown\u20106 results in the formation of \u201cmasked\u201d terminal Ni<jats:sup>II<\/jats:sup> sulfides, [K(18\u2010crown\u20106)][L<jats:sup>R<\/jats:sup>Ni(S)] (<jats:bold>3<\/jats:bold>: R=Me; <jats:bold>4<\/jats:bold>: R=<jats:italic>t<\/jats:italic>Bu), also in good yields. An X\u2010ray crystallographic analysis of these complexes suggests that they feature partial multiple\u2010bond character in their Ni\uf8ffS linkages. Addition of N<jats:sub>2<\/jats:sub>O to a toluene solution of <jats:bold>4<\/jats:bold> provides [K(18\u2010crown\u20106)][L<jats:sup><jats:italic>t<\/jats:italic>Bu<\/jats:sup>Ni(SN\uf8feNO)], which features the first example of a thiohyponitrite (\u03ba<jats:sup>2<\/jats:sup>\u2010[SN\uf8feNO]<jats:sup>2\u2212<\/jats:sup>) ligand.<\/jats:p>","DOI":"10.1002\/anie.201508232","type":"journal-article","created":{"date-parts":[[2015,10,13]],"date-time":"2015-10-13T11:28:35Z","timestamp":1444735715000},"page":"14956-14959","source":"Crossref","is-referenced-by-count":32,"title":["Synthesis of a \u201cMasked\u201d Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide"],"prefix":"10.1002","volume":"54","author":[{"given":"Nathaniel 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