{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,19]],"date-time":"2026-10-19T19:59:55Z","timestamp":1792439995298,"version":"4.5.0"},"reference-count":63,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2015,11,24]],"date-time":"2015-11-24T00:00:00Z","timestamp":1448323200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Funded Access"},{"DOI":"10.13039\/501100000266","name":"EPSRC","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2016,1,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A redox\u2010neutral palladium(II)\u2010catalyzed conversion of aryl, heteroaryl, and alkenyl boronic acids into sulfinate intermediates, and onwards to sulfones and sulfonamides, has been realized. A simple Pd(OAc)\n                    <jats:sub>2<\/jats:sub>\n                    catalyst, in combination with the sulfur dioxide surrogate 1,4\u2010diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO), is sufficient to achieve rapid and high\u2010yielding conversion of the boronic acids into the corresponding sulfinates. Addition of C\u2010 or N\u2010based electrophiles then allows conversion into sulfones and sulfonamides, respectively, in a one\u2010pot, two\u2010step process.\n                  <\/jats:p>","DOI":"10.1002\/anie.201508370","type":"journal-article","created":{"date-parts":[[2015,11,24]],"date-time":"2015-11-24T07:32:34Z","timestamp":1448350354000},"page":"747-750","source":"Crossref","is-referenced-by-count":238,"title":["Palladium(II)\u2010Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox\u2010Neutral, Phosphine\u2010Free Transformation"],"prefix":"10.1002","volume":"55","author":[{"given":"Alex S.","family":"Deeming","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Claire J.","family":"Russell","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael C.","family":"Willis","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,11,24]]},"reference":[{"key":"e_1_2_3_1_2","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ed1003806"},{"key":"e_1_2_3_3_2","first-page":"72","volume":"11","author":"Smith D. 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