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Notably, this novel methodology avoids hydrogenation of the aromatic ring and allows methoxylation of substituted imides with good to excellent selectivity for one of the carbonyl groups. The reported method opens the door to the development of new processes for the selective synthesis of various functionalized N\u2010heterocyclic compounds. As an example, intramolecular reductive couplings to afford tricyclic compounds are presented for the first time.<\/jats:p>","DOI":"10.1002\/anie.201508575","type":"journal-article","created":{"date-parts":[[2015,11,11]],"date-time":"2015-11-11T07:06:39Z","timestamp":1447225599000},"page":"387-391","source":"Crossref","is-referenced-by-count":38,"title":["Selective Ruthenium\u2010Catalyzed Reductive Alkoxylation and Amination of Cyclic Imides"],"prefix":"10.1002","volume":"55","author":[{"given":"Jose R.","family":"Cabrero\u2010Antonino","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iv\u00e1n","family":"Sorribes","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kathrin","family":"Junge","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Beller","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,11,11]]},"reference":[{"key":"e_1_2_4_1_2","unstructured":"For selected examples see:"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(88)80015-7"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00178a038"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00077a048"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199523911"},{"key":"e_1_2_4_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951072116"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00106a072"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1097\/00001813-200201000-00001"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0306182"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020083x"},{"key":"e_1_2_4_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b601433j"},{"key":"e_1_2_4_11_2","doi-asserted-by":"publisher","DOI":"10.1358\/dot.2011.47.4.1590792"},{"key":"e_1_2_4_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201109221"},{"key":"e_1_2_4_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201109221"},{"key":"e_1_2_4_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo401450j"},{"key":"e_1_2_4_14_2","unstructured":"For selected examples see:"},{"key":"e_1_2_4_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00059a023"},{"key":"e_1_2_4_16_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2006-942462"},{"key":"e_1_2_4_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja054216i"},{"key":"e_1_2_4_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0711570"},{"key":"e_1_2_4_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo901628a"},{"key":"e_1_2_4_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200906036"},{"key":"e_1_2_4_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200906036"},{"key":"e_1_2_4_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol300471a"},{"key":"e_1_2_4_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc43838d"},{"key":"e_1_2_4_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201300055"},{"key":"e_1_2_4_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC08717H"},{"key":"e_1_2_4_25_2","unstructured":"For selected examples see:"},{"key":"e_1_2_4_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm9502201"},{"key":"e_1_2_4_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo000118y"},{"key":"e_1_2_4_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo0156316"},{"key":"e_1_2_4_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2007.05.035"},{"key":"e_1_2_4_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201101014"},{"key":"e_1_2_4_31_2","unstructured":"\u00a0"},{"key":"e_1_2_4_32_2","first-page":"1","volume-title":"Catalytic Reduction of Amides Avoiding LiAlH4 and B2H6 in Sustainable Catalysis: Challenges and Practices for the Pharmaceutical and Fine Chemical Industries","author":"Dodds D. 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