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Herein, we describe the design of unconventional catalysts based on bulk materials with a certain defect structure, for example, ZrO<jats:sub>2<\/jats:sub> promoted with other metal oxides. Comprehensive characterization supports the hypothesis that coordinatively unsaturated Zr cations are the active sites for propane dehydrogenation. Their concentration can be adjusted by varying the kind of ZrO<jats:sub>2<\/jats:sub> promoter and\/or supporting tiny amounts of hydrogenation\u2010active metal. Accordingly designed Cu(0.05\u2005wt\u2009%)\/ZrO<jats:sub>2<\/jats:sub>\u2010La<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> showed industrially relevant activity and durability over ca. 240\u2005h on stream in a series of 60\u2005dehydrogenation and oxidative regeneration cycles between 550 and 625\u2009\u00b0C.<\/jats:p>","DOI":"10.1002\/anie.201508731","type":"journal-article","created":{"date-parts":[[2015,11,13]],"date-time":"2015-11-13T11:06:37Z","timestamp":1447412797000},"page":"15880-15883","source":"Crossref","is-referenced-by-count":216,"title":["ZrO<sub>2<\/sub>\u2010Based Alternatives to Conventional Propane Dehydrogenation Catalysts: Active Sites, Design, and Performance"],"prefix":"10.1002","volume":"54","author":[{"given":"Tatyana","family":"Otroshchenko","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey","family":"Sokolov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mariana","family":"Stoyanova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vita A.","family":"Kondratenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Uwe","family":"Rodemerck","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Linke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evgenii V.","family":"Kondratenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,11,13]]},"reference":[{"key":"e_1_2_4_1_2","unstructured":"\u00a0"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1226840"},{"key":"e_1_2_4_3_2","unstructured":"U.\u2005S. 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