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These methods enable the enantioselective synthesis of \u03b1\u20102\u2010propenyl benzyl motifs, which are important scaffolds in natural products and pharmaceuticals. A variety of cyclic and acyclic allylic carbonates are competent electrophilic partners furnishing the products in excellent enantioselectivity (up to 99\u2009% <jats:italic>ee<\/jats:italic> and 92\u2009% yield). 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