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Aryl sulfonamides add to benzyne upon fluoride activation, and then undergo an aryl Truce\u2013Smiles rearrangement to afford biaryls with sulfur dioxide extrusion. The reaction proceeds under simple reaction conditions and has excellent scope for the synthesis of sterically hindered atropisomeric biaryl amines.<\/jats:p>","DOI":"10.1002\/anie.201510236","type":"journal-article","created":{"date-parts":[[2016,1,14]],"date-time":"2016-01-14T04:07:19Z","timestamp":1452744439000},"page":"2450-2453","source":"Crossref","is-referenced-by-count":116,"title":["Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce\u2013Smiles Rearrangement"],"prefix":"10.1002","volume":"55","author":[{"given":"Catherine M.","family":"Holden","sequence":"first","affiliation":[{"name":"School of Chemistry The University of Manchester  Oxford Road Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shariar M. 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