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Its selective adsorption is derived from the breathing effect induced by a guest triggered alkyl transformation. This feature allows the crystal to take up 2.5\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup> of chloroform with high adsorption selectivity (CHCl<jats:sub>3<\/jats:sub>\/EA &gt;2000 for example), implying a potential application in sorption separation and chemical sensors.<\/jats:p>","DOI":"10.1002\/anie.201510637","type":"journal-article","created":{"date-parts":[[2016,2,2]],"date-time":"2016-02-02T22:02:29Z","timestamp":1454450549000},"page":"3378-3381","source":"Crossref","is-referenced-by-count":24,"title":["Guest\u2010Induced Breathing Effect in a Flexible Molecular Crystal"],"prefix":"10.1002","volume":"55","author":[{"given":"Yujie","family":"Sheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Engineering Department of Chemistry East China University of Science and Technology  Shanghai 200237 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qibin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Engineering Department of Chemistry East China University of Science and Technology  Shanghai 200237 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Junyao","family":"Yao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Engineering Department of Chemistry East China University of Science and Technology  Shanghai 200237 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yunxiang","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Engineering Department of Chemistry East China University of Science and Technology  Shanghai 200237 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Honglai","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Engineering Department of Chemistry East China University of Science and Technology  Shanghai 200237 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sheng","family":"Dai","sequence":"additional","affiliation":[{"name":"Chemical Sciences Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"},{"name":"Department of Chemistry University of Tennessee  Knoxville TN 37996-1600 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,2,2]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.444"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4035"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400265x"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703934"},{"key":"e_1_2_2_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703934"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.873"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410077"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410077"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4129795"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja506577g"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm01867h"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b01346"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201351"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm9012969"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200502844"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200502844"},{"key":"e_1_2_2_17_1","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic200937u"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305754f"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm503533r"},{"key":"e_1_2_2_21_1","unstructured":"\u00a0"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CE01879F"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576715004938"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8024092"},{"key":"e_1_2_2_25_1","unstructured":"\u00a0"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6223(00)00161-5"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm502942w"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/la501594t"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep06247"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2011.08.020"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9933386"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CE00547G"},{"key":"e_1_2_2_34_1","unstructured":"It should be noted that PMC-2 shows localized uncertainty at the tip of the alkyl chains. 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