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The products [(LFe)<jats:sub>4<\/jats:sub>(\u03bc<jats:sub>4<\/jats:sub>\u2010\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>\u2010P<jats:sub>8<\/jats:sub>)] (L=L<jats:sup>1<\/jats:sup> (<jats:bold>2\u2009a<\/jats:bold>), L<jats:sup>2<\/jats:sup> (<jats:bold>2\u2009b<\/jats:bold>)) containing a P<jats:sub>8<\/jats:sub> core were obtained by the reaction of <jats:bold>1\u2009a,b<\/jats:bold> with P<jats:sub>4<\/jats:sub> in toluene at room temperature. Using a slightly more sterically encumbered ligand in <jats:bold>1\u2009c<\/jats:bold> results in the formation of [(L<jats:sup>3<\/jats:sup>Fe)<jats:sub>2<\/jats:sub>(\u03bc\u2010\u03b7<jats:sup>4<\/jats:sup>:\u03b7<jats:sup>4<\/jats:sup>\u2010P<jats:sub>4<\/jats:sub>)] (<jats:bold>2\u2009c<\/jats:bold>), possessing a cyclo\u2010P<jats:sub>4<\/jats:sub> moiety. Compounds <jats:bold>2\u2009a<\/jats:bold>\u2013<jats:bold>c<\/jats:bold> were comprehensively characterized and their electronic structures investigated by SQUID magnetization and <jats:sup>57<\/jats:sup>Fe M\u00f6ssbauer spectroscopy as well as by DFT methods.<\/jats:p>","DOI":"10.1002\/anie.201510716","type":"journal-article","created":{"date-parts":[[2016,2,29]],"date-time":"2016-02-29T08:33:59Z","timestamp":1456734839000},"page":"4340-4344","source":"Crossref","is-referenced-by-count":77,"title":["Influence of the nacnac Ligand in Iron(I)\u2010Mediated P<sub>4<\/sub> Transformations"],"prefix":"10.1002","volume":"55","author":[{"given":"Fabian","family":"Spitzer","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Gra\u00dfl","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eva M.","family":"Zolnhofer","sequence":"additional","affiliation":[{"name":"Friedrich-Alexander University Erlangen-N\u00fcrnberg (FAU) Department of Chemistry and Pharmacy Inorganic Chemistry  Egerlandstrasse 1 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Karsten","family":"Meyer","sequence":"additional","affiliation":[{"name":"Friedrich-Alexander University Erlangen-N\u00fcrnberg (FAU) Department of Chemistry and Pharmacy Inorganic Chemistry  Egerlandstrasse 1 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,2,29]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17449a"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_2_5_1","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005029"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005029"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5107282"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10074"},{"key":"e_1_2_2_12_1","unstructured":"\u00a0"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00147A"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409469"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902820"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411451"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411451"},{"key":"e_1_2_2_17_1","unstructured":"The term \u201crealgar-type\u201d P8moiety for the tricyclo[3.3.0.03 7]octaphosphane ligand comes from its analogy to the isostructural realgar (As4S4) molecule."},{"key":"e_1_2_2_18_1","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","unstructured":"For2\u2009a b ccalculated at the BP86\/def2-SVP level. 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