{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T04:52:38Z","timestamp":1789879958260,"version":"4.0.1"},"reference-count":28,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2016,2,8]],"date-time":"2016-02-08T00:00:00Z","timestamp":1454889600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"National Energy Research Scientific Computing Center"},{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Special Funds for Major State Basic Research"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2016,3,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    At ultrahigh pressure (&gt;110\u2005GPa), H\n                    <jats:sub>2<\/jats:sub>\n                    S is converted into a metallic phase that becomes superconducting with a record T\n                    <jats:sub>c<\/jats:sub>\n                    of approximately 200\u2005K. It has been proposed that the superconducting phase is body\u2010centered cubic H\n                    <jats:sub>3<\/jats:sub>\n                    S (Im\n                    <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie201511347-math-0001.png\" xlink:title=\"urn:x-wiley:14337851:media:anie201511347:anie201511347-math-0001\"\/>\n                    m, a=3.089\u2005\u00c5) resulting from the decomposition reaction 3\u2009H\n                    <jats:sub>2<\/jats:sub>\n                    S\u21922\u2009H\n                    <jats:sub>3<\/jats:sub>\n                    S+S. The analogy between H\n                    <jats:sub>2<\/jats:sub>\n                    S and H\n                    <jats:sub>2<\/jats:sub>\n                    O led us to a very different conclusion. The well\u2010known dissociation of water into H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    increases by orders of magnitude under pressure. H\n                    <jats:sub>2<\/jats:sub>\n                    S is anticipated to behave similarly under pressure, with the dissociation process 2\u2009H\n                    <jats:sub>2<\/jats:sub>\n                    S\u2192H\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    +SH\n                    <jats:sup>\u2212<\/jats:sup>\n                    leading to the perovskite structure (SH\n                    <jats:sup>\u2212<\/jats:sup>\n                    )(H\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    ). This phase consists of corner\u2010sharing SH\n                    <jats:sub>6<\/jats:sub>\n                    octahedra with SH\n                    <jats:sup>\u2212<\/jats:sup>\n                    ions at each A\u2005site (the centers of the S\n                    <jats:sub>8<\/jats:sub>\n                    cubes). DFT calculations show that the perovskite (SH\n                    <jats:sup>\u2212<\/jats:sup>\n                    )(H\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    ) is thermodynamically more stable than the Im\n                    <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie201511347-math-0002.png\" xlink:title=\"urn:x-wiley:14337851:media:anie201511347:anie201511347-math-0002\"\/>\n                    m structure of H\n                    <jats:sub>3<\/jats:sub>\n                    S, and suggest that the A\u2005site hydrogen atoms are most likely fluxional even at T\n                    <jats:sub>c<\/jats:sub>\n                    \u2009.\n                  <\/jats:p>","DOI":"10.1002\/anie.201511347","type":"journal-article","created":{"date-parts":[[2016,2,8]],"date-time":"2016-02-08T11:34:53Z","timestamp":1454931293000},"page":"3682-3684","source":"Crossref","is-referenced-by-count":39,"title":["Structure and Composition of the 200\u2005K\u2010Superconducting Phase of H\n                    <sub>2<\/sub>\n                    S at Ultrahigh Pressure: The Perovskite (SH\n                    <sup>\u2212<\/sup>\n                    )(H\n                    <sub>3<\/sub>\n                    S\n                    <sup>+<\/sup>\n                    )"],"prefix":"10.1002","volume":"55","author":[{"given":"Elijah E.","family":"Gordon","sequence":"first","affiliation":[{"name":"Department of Chemistry North Carolina State University  Raleigh NC 27695-8204 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ke","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physical Sciences (Ministry of Education) State Key Laboratory of Surface Physics Department of Physics Fudan University  Shanghai 200433 P. R. China"},{"name":"Collaborative Innovation Center of Advanced Microstructures  Nanjing 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongjun","family":"Xiang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Computational Physical Sciences (Ministry of Education) State Key Laboratory of Surface Physics Department of Physics Fudan University  Shanghai 200433 P. R. China"},{"name":"Collaborative Innovation Center of Advanced Microstructures  Nanjing 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Annette","family":"Bussmann\u2010Holder","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Festk\u00f6rperforschung  Heisenbergstrasse 1 70569 Stuttgart Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reinhard K.","family":"Kremer","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Festk\u00f6rperforschung  Heisenbergstrasse 1 70569 Stuttgart Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arndt","family":"Simon","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Festk\u00f6rperforschung  Heisenbergstrasse 1 70569 Stuttgart Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00fcrgen","family":"K\u00f6hler","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Festk\u00f6rperforschung  Heisenbergstrasse 1 70569 Stuttgart Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Myung\u2010Hwan","family":"Whangbo","sequence":"additional","affiliation":[{"name":"Department of Chemistry North Carolina State University  Raleigh NC 27695-8204 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,2,8]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14964"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.91.060511"},{"key":"e_1_2_2_3_1","unstructured":"M. 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