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The polyoxovanadate core undergoes transformation to a <jats:italic>D<\/jats:italic><jats:sub>3<jats:italic>d<\/jats:italic><\/jats:sub> configuration upon acidification, and reverts back to its original <jats:italic>C<\/jats:italic><jats:sub>2<jats:italic>h<\/jats:italic><\/jats:sub> structure upon addition of base. Chromism was observed for the silver(I) thiolate cluster during the configurational change of the central polyoxovanadate core; the color of the solution changes reversibly from green to dark yellow. This work represents the first reported example of chromic polyoxometalate\u2010templated silver(I) thiolate shells that respond to external acid\u2013base stimuli. It also represents an important advance in providing crystallographic proof that structural transformations occur in a nanoscale core\u2013shell cluster.<\/jats:p>","DOI":"10.1002\/anie.201511765","type":"journal-article","created":{"date-parts":[[2016,2,16]],"date-time":"2016-02-16T09:53:24Z","timestamp":1455616404000},"page":"3699-3703","source":"Crossref","is-referenced-by-count":133,"title":["Acid\u2013Base\u2010Triggered Structural Transformation of a Polyoxometalate Core Inside a Dodecahedrane\u2010like Silver Thiolate Shell"],"prefix":"10.1002","volume":"55","author":[{"given":"Hong","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry College of Pharmacy Jiamusi University  Jiamusi 154004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao\u2010Yu","family":"Song","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Pharmacy Jiamusi University  Jiamusi 154004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u2010Wu","family":"Huang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Pharmacy Jiamusi University  Jiamusi 154004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei\u2010Jia","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Pharmacy Jiamusi University  Jiamusi 154004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang\u2010Quan","family":"Zang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang\u2010Gang","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Pharmacy Jiamusi University  Jiamusi 154004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,2,16]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4NR05794E"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00007"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5b00934"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35252D"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b07088"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01232"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704249"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704249"},{"key":"e_1_2_2_10_1","unstructured":"\u00a0"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201500201"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5NR01222H"},{"key":"e_1_2_2_13_2","first-page":"1641","author":"Sun D.","year":"2011","journal-title":"Chem. 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