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Experimental and theoretical studies revealed the peculiar effect of phosphanylidene phosphorane substituent, which is a stronger \u03c0\u2010donor towards germanium than an amino group is. Because of the weak phosphorus\u2013germanium \u03c0\u2010bond, this new germylene compound shows an enhanced reactivity compared to classical N\u2010heterocyclic germylenes.<\/jats:p>","DOI":"10.1002\/anie.201511956","type":"journal-article","created":{"date-parts":[[2016,3,8]],"date-time":"2016-03-08T21:29:47Z","timestamp":1457472587000},"page":"4753-4758","source":"Crossref","is-referenced-by-count":106,"title":["A Stable Heterocyclic Amino(phosphanylidene\u2010\u03c3<sup>4<\/sup>\u2010phosphorane) Germylene"],"prefix":"10.1002","volume":"55","author":[{"given":"Natalia","family":"Del\u2005Rio","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Toulouse, UPS, and CNRS, LHFA UMR 5069  118 route de Narbonne 31062 Toulouse cedex 9 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antoine","family":"Baceiredo","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Toulouse, UPS, and CNRS, LHFA UMR 5069  118 route de Narbonne 31062 Toulouse 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