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Treatment of <jats:bold>1<\/jats:bold> with I<jats:sub>2<\/jats:sub> or MeI yielded the oxidative addition products (NIPr)<jats:sub>2<\/jats:sub>SnI<jats:sub>2<\/jats:sub> and (NIPr)<jats:sub>2<\/jats:sub>Sn(Me)I, respectively. In contrast, the reaction of <jats:bold>1<\/jats:bold> with one equivalent of Me<jats:sub>3<\/jats:sub>SiCl resulted in the formation of Me<jats:sub>3<\/jats:sub>SiNIPr and the chlorostannylene dimer [NIPrSnCl]<jats:sub>2<\/jats:sub>. Moreover, the substitution reaction of compound <jats:bold>1<\/jats:bold> with MeLi led to the formation of the methyl\u2010substituted stannate (NIPr)<jats:sub>2<\/jats:sub>Sn(Li)Me.<\/jats:p>","DOI":"10.1002\/anie.201602178","type":"journal-article","created":{"date-parts":[[2016,4,22]],"date-time":"2016-04-22T00:55:13Z","timestamp":1461286513000},"page":"6983-6987","source":"Crossref","is-referenced-by-count":41,"title":["A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin\u20102\u2010imino)stannylenoid"],"prefix":"10.1002","volume":"55","author":[{"given":"Tatsumi","family":"Ochiai","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Anorganische Chemie Technische Universit\u00e4t Berlin  Strasse des 17. 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Juni 135 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6685-6352","authenticated-orcid":false,"given":"Shigeyoshi","family":"Inoue","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Anorganische Chemie Technische Universit\u00e4t Berlin  Strasse des 17. 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