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The deformation of host water cages at the cubic\u2013tetragonal phase transition of 2\u2010propanol+CH<jats:sub>4<\/jats:sub> hydrate, but not 1\u2010propanol+CH<jats:sub>4<\/jats:sub> hydrate, was observed below about 110\u2005K. It is shown that the deformation of the host water cages of 2\u2010propanol+CH<jats:sub>4<\/jats:sub> hydrate can be explained by the restriction of the motion of 2\u2010propanol within the 5<jats:sup>12<\/jats:sup>6<jats:sup>4<\/jats:sup> host water cages. This result provides a low\u2010temperature structure due to a temperature\u2010induced symmetry\u2010lowering transition of clathrate hydrate. This is the first example of a cubic structure of the common clathrate hydrate families at a fixed composition.<\/jats:p>","DOI":"10.1002\/anie.201602733","type":"journal-article","created":{"date-parts":[[2016,6,27]],"date-time":"2016-06-27T08:19:35Z","timestamp":1467015575000},"page":"9287-9291","source":"Crossref","is-referenced-by-count":24,"title":["Phase Transition of a Structure\u2005II Cubic Clathrate Hydrate to a Tetragonal Form"],"prefix":"10.1002","volume":"55","author":[{"given":"Satoshi","family":"Takeya","sequence":"first","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST)  Central 5, 1-1-1 Higashi Tsukuba 305-8565 Ibaraki Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hiroshi","family":"Fujihisa","sequence":"additional","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST)  Central 5, 1-1-1 Higashi Tsukuba 305-8565 Ibaraki Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hiroshi","family":"Yamawaki","sequence":"additional","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST)  Central 5, 1-1-1 Higashi Tsukuba 305-8565 Ibaraki Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yoshito","family":"Gotoh","sequence":"additional","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST)  Central 5, 1-1-1 Higashi Tsukuba 305-8565 Ibaraki Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ryo","family":"Ohmura","sequence":"additional","affiliation":[{"name":"Keio University  3-14-1 Hiyoshi Kohoku-Ku Yokohama 223-8522 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Saman","family":"Alavi","sequence":"additional","affiliation":[{"name":"National Research Council of Canada  100 Sussex Dr. Ottawa ON K1A0R6 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"John A.","family":"Ripmeester","sequence":"additional","affiliation":[{"name":"National Research Council of Canada  100 Sussex Dr. Ottawa ON K1A0R6 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,6,27]]},"reference":[{"key":"e_1_2_2_1_1","volume-title":"Comprehensive Supramolecular Chemistry, Vol.\u20056","author":"Jeffrey G. 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