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The new anion represents the first example of face\u2010fused nine\u2010atom molecular clusters. The two clusters are identical elongated tricapped trigonal prisms of <jats:italic>nido<\/jats:italic>\u2010[Sn<jats:sub>8<\/jats:sub>Ni(CO)]<jats:sup>6\u2212<\/jats:sup> with nickel at one of the capping positions. They are fused along a triangular face adjacent to a trigonal prismatic base and made of two Sn and one Ni atoms. The new anion is structurally characterized by single\u2010crystal X\u2010ray diffraction in the compound (K[222\u2010crypt])<jats:sub>4<\/jats:sub>[Sn<jats:sub>14<\/jats:sub>Ni(CO)]\u22c5DMF. Its presence in solution is corroborated by electrospray mass spectrometry.<\/jats:p>","DOI":"10.1002\/anie.201602837","type":"journal-article","created":{"date-parts":[[2016,4,21]],"date-time":"2016-04-21T11:24:14Z","timestamp":1461237854000},"page":"6721-6724","source":"Crossref","is-referenced-by-count":24,"title":["Cluster Fusion: Face\u2010Fused Nine\u2010Atom Deltahedral Clusters in [Sn<sub>14<\/sub>Ni(CO)]<sup>4\u2212<\/sup>"],"prefix":"10.1002","volume":"55","author":[{"given":"Luis G.","family":"Perla","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Notre Dame  Notre Dame IN 46556 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4425-868X","authenticated-orcid":false,"given":"Slavi C.","family":"Sevov","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Notre Dame  Notre Dame IN 46556 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,4,21]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000218)39:4<670::AID-ANIE670>3.0.CO;2-M"},{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000218)112:4<682::AID-ANGE682>3.0.CO;2-3"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00176a020"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50046a019"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604077"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604077"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990356x"},{"key":"e_1_2_2_6_1","first-page":"4314","volume":"123","author":"Jemmis E. 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