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The precursor BaCe\n                    <jats:sub>0.5<\/jats:sub>\n                    Fe\n                    <jats:sub>0.5<\/jats:sub>\n                    O\n                    <jats:sub>\n                      3\u2212\n                      <jats:italic>\u03b4<\/jats:italic>\n                    <\/jats:sub>\n                    decomposes on calcination at 1370\u2009\u00b0C for 10\u2005h into two thermodynamically stable oxides with perovskite structures: the cerium\u2010rich oxide BaCe\n                    <jats:sub>0.85<\/jats:sub>\n                    Fe\n                    <jats:sub>0.15<\/jats:sub>\n                    O\n                    <jats:sub>\n                      3\u2212\n                      <jats:italic>\u03b4<\/jats:italic>\n                    <\/jats:sub>\n                    (BCF8515) and the iron\u2010rich oxide BaCe\n                    <jats:sub>0.15<\/jats:sub>\n                    Fe\n                    <jats:sub>0.85<\/jats:sub>\n                    O\n                    <jats:sub>\n                      3\u2212\n                      <jats:italic>\u03b4<\/jats:italic>\n                    <\/jats:sub>\n                    (BCF1585), 50\u2005mol\u2009% each. In the resulting dual\u2010phase material, the orthorhombic perovskite BCF8515 acts as the main proton conductor and the cubic perovskite BCF1585 as the main electron conductor. The dual\u2010phase membrane shows an extremely high H\n                    <jats:sub>2<\/jats:sub>\n                    permeation flux of 0.76\u2005mL\u2009min\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2005cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 950\u2009\u00b0C with 1.0\u2005mm thickness. This auto\u2010demixing concept should be applicable to the synthesis of other ionic\u2010electronic conducting ceramics.\n                  <\/jats:p>","DOI":"10.1002\/anie.201604035","type":"journal-article","created":{"date-parts":[[2016,7,27]],"date-time":"2016-07-27T03:58:54Z","timestamp":1469591934000},"page":"10895-10898","source":"Crossref","is-referenced-by-count":103,"title":["A Dual\u2010Phase Ceramic Membrane with Extremely High H\n                    <sub>2<\/sub>\n                    Permeation Flux Prepared by Autoseparation of a Ceramic Precursor"],"prefix":"10.1002","volume":"55","author":[{"given":"Shunfan","family":"Cheng","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  510640 Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanjie","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China 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