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The formation\/dissociation of a dynamic B\u2212N coordination bond can be used for the solution\u2010processed fabrication of semiconducting films of polycyclic aromatic hydrocarbon (PAH) materials. The poor solubility of a boron\u2010containing PAH in chloroform, toluene, and chlorobenzene was significantly improved by addition of minor amounts (1\u2005wt\u2009% of solvent) of pyridine derivatives, as their coordination to the boron atom suppresses the inherent propensity of the PAHs to form \u03c0\u2010stacks. Spin\u2010coating solutions of the thus formed Lewis acid\u2013base complexes resulted in the formation of amorphous thin films, which could be converted into polycrystalline films of the boron\u2010containing PAH upon thermal annealing. Organic thin\u2010film transistors prepared by this solution process displayed typical p\u2010type characteristics.<\/jats:p>","DOI":"10.1002\/anie.201605221","type":"journal-article","created":{"date-parts":[[2016,8,31]],"date-time":"2016-08-31T13:05:00Z","timestamp":1472648700000},"page":"11984-11988","source":"Crossref","is-referenced-by-count":59,"title":["A Soluble Dynamic Complex Strategy for the Solution\u2010Processed Fabrication of Organic Thin\u2010Film Transistors of a Boron\u2010Containing Polycyclic Aromatic Hydrocarbon"],"prefix":"10.1002","volume":"55","author":[{"given":"Kyohei","family":"Matsuo","sequence":"first","affiliation":[{"name":"Department of Chemistry, Graduate School of Science Nagoya University, Furo, Chikusa  Nagoya 464-8602 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shohei","family":"Saito","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science Nagoya University, Furo, Chikusa  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