{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T18:38:51Z","timestamp":1792175931886,"version":"4.4.0"},"reference-count":53,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2016,10,6]],"date-time":"2016-10-06T00:00:00Z","timestamp":1475712000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2016,10,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Direct asymmetric synthesis of <jats:italic>N<\/jats:italic>\u2010chiral amine oxides was accomplished (up to 91:9 e.r.) by means of a bimetallic titanium catalyst. A hydroxy group situated at the \u03b3\u2010position of the N\u2005stereocenter enables the desired N\u2010oxidation through dynamic kinetic resolution of the trivalent amine substrates. The method was further extended to the kinetic resolution of racemic \u03b3\u2010amino alcohols with a preexisting stereocenter, giving an important class of enantioenriched (up to 99.9:0.1 e.r.) building blocks that are otherwise difficult to synthesize.<\/jats:p>","DOI":"10.1002\/anie.201606354","type":"journal-article","created":{"date-parts":[[2016,9,21]],"date-time":"2016-09-21T12:54:14Z","timestamp":1474462454000},"page":"13043-13046","source":"Crossref","is-referenced-by-count":33,"title":["Catalytic Asymmetric Synthesis of N\u2010Chiral Amine Oxides"],"prefix":"10.1002","volume":"55","author":[{"given":"Sukalyan","family":"Bhadra","sequence":"first","affiliation":[{"name":"Molecular Catalyst Research Center Chubu University  1200, Matsumoto-cho, Kasugai Aichi 487-8501 Japan"},{"name":"Inorganic Materials and Catalysis Division CSIR-Central Salt and Marine Chemicals Research Institute  G.B. Marg, Bhavnagar 364002 Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hisashi","family":"Yamamoto","sequence":"additional","affiliation":[{"name":"Molecular Catalyst Research Center Chubu University  1200, Matsumoto-cho, Kasugai Aichi 487-8501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,10,6]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For an overview see:"},{"key":"e_1_2_2_2_2","volume-title":"Asymmetric Synthesis, Vol.\u20054","year":"1983"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a009"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460848"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460848"},{"key":"e_1_2_2_5_2","first-page":"1","volume-title":"Organosulfur Chemistry in Asymmetric Synthesis","author":"Kagan H. 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