{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T19:44:15Z","timestamp":1791402255759,"version":"4.3.3"},"reference-count":125,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2016,8,30]],"date-time":"2016-08-30T00:00:00Z","timestamp":1472515200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","award":["257891"],"award-info":[{"award-number":["257891"]}],"id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Compounds with stereogenic phosphorus atoms are frequently used as ligands for transition\u2010metal as well as organocatalysts. A direct catalytic enantioselective method for the synthesis of <jats:italic>P<\/jats:italic>\u2010chiral compounds from easily accessible diaryl phosphinamides is presented. The use of rhodium(III) complexes equipped with a suitable atropochiral cyclopentadienyl ligand is shown to enable an enantiodetermining C\u2212H activation step. Upon trapping with alkynes, a broad variety of cyclic phosphinamides with a stereogenic phosphorus(V) atom are formed in high yields and enantioselectivities. Moreover, these can be reduced enantiospecifically to <jats:italic>P<\/jats:italic>\u2010chiral phosphorus(III) compounds.<\/jats:p>","DOI":"10.1002\/anie.201606637","type":"journal-article","created":{"date-parts":[[2016,8,30]],"date-time":"2016-08-30T07:47:21Z","timestamp":1472543241000},"page":"364-367","source":"Crossref","is-referenced-by-count":264,"title":["Rhodium(III)\u2010Catalyzed Enantiotopic C\u2212H Activation Enables Access to <i>P<\/i>\u2010Chiral Cyclic Phosphinamides"],"prefix":"10.1002","volume":"56","author":[{"given":"Yang","family":"Sun","sequence":"first","affiliation":[{"name":"Laboratory of Asymmetric Catalysis and Synthesis, EPFL SB ISIC LCSA, BCH 4305  1015 Lausanne Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolai","family":"Cramer","sequence":"additional","affiliation":[{"name":"Laboratory of Asymmetric Catalysis and Synthesis, EPFL SB ISIC LCSA, BCH 4305  1015 Lausanne 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