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The corresponding derivatives Bi(NON<jats:sup>R<\/jats:sup>)(PCy<jats:sub>2<\/jats:sub>) are stable. Reaction of the isolated Bi<jats:sup>II<\/jats:sup> radical <jats:sup>.<\/jats:sup>Bi(NON<jats:sup>Ar<\/jats:sup>) with white phosphorus (P<jats:sub>4<\/jats:sub>) proceeds with the reversible and selective activation of a single P\u2212P bond to afford the bimetallic \u03bc,\u03b7<jats:sup>1:1<\/jats:sup>\u2010bicyclo[1.1.0]tetraphosphabutane compound.<\/jats:p>","DOI":"10.1002\/anie.201608615","type":"journal-article","created":{"date-parts":[[2016,10,26]],"date-time":"2016-10-26T08:17:45Z","timestamp":1477469865000},"page":"14798-14801","source":"Crossref","is-referenced-by-count":99,"title":["Bi\u2212P Bond Homolysis as a Route to Reduced Bismuth Compounds and Reversible Activation of P<sub>4<\/sub>"],"prefix":"10.1002","volume":"55","author":[{"given":"Ryan J.","family":"Schwamm","sequence":"first","affiliation":[{"name":"School of Chemical and Physical Sciences Victoria University of Wellington  Wellington 6012 New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Lein","sequence":"additional","affiliation":[{"name":"School of Chemical and Physical Sciences Victoria University of Wellington  Wellington 6012 New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3558-271X","authenticated-orcid":false,"given":"Martyn P.","family":"Coles","sequence":"additional","affiliation":[{"name":"School of Chemical and Physical Sciences Victoria University of Wellington  Wellington 6012 New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christopher M.","family":"Fitchett","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Canterbury  Christchurch New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,10,26]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39940001987"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm960606f"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a012"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400020d"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X65004140"},{"key":"e_1_2_2_7_1","first-page":"2235","volume":"62","author":"Frost A. 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