{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T20:17:17Z","timestamp":1793305037948,"version":"4.5.0"},"reference-count":68,"publisher":"Wiley","issue":"50","license":[{"start":{"date-parts":[[2016,11,15]],"date-time":"2016-11-15T00:00:00Z","timestamp":1479168000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2016,12,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report fundamental studies on the reactivity of the 2\u2010arsaethynolate anion (AsCO<jats:sup>\u2212<\/jats:sup>), a species that has only recently become synthetically accessible. The reaction of AsCO<jats:sup>\u2212<\/jats:sup> with the bulky stannylene Ter<jats:sub>2<\/jats:sub>Sn (Ter=2,6\u2010bis[2,4,6\u2010trimethylphenyl]phenyl) is described, which leads to the unexpected formation of a [Ter<jats:sub>3<\/jats:sub>Sn<jats:sub>2<\/jats:sub>As<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> cluster compound. On the reaction pathway to this cluster, several intermediates were identified and characterized. After the initial association of AsCO<jats:sup>\u2212<\/jats:sup> to Ter<jats:sub>2<\/jats:sub>Sn, decarbonylation occurs to give an anion featuring monocoordinate arsenic, [Ter<jats:sub>2<\/jats:sub>SnAs]<jats:sup>\u2212<\/jats:sup>. Both species are not stable under ambient conditions, and [Ter<jats:sub>2<\/jats:sub>SnAs]<jats:sup>\u2212<\/jats:sup> rearranges to form [TerSnAsTer]<jats:sup>\u2212<\/jats:sup>, an unprecedented anionic mixed Group\u200514\/15 alkene analogue.<\/jats:p>","DOI":"10.1002\/anie.201609309","type":"journal-article","created":{"date-parts":[[2016,11,16]],"date-time":"2016-11-16T18:30:41Z","timestamp":1479321041000},"page":"15515-15519","source":"Crossref","is-referenced-by-count":55,"title":["A Monoanionic Arsenide Source: Decarbonylation of the 2\u2010Arsaethynolate Anion upon Reaction with Bulky Stannylenes"],"prefix":"10.1002","volume":"55","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7831-1410","authenticated-orcid":false,"given":"Alexander","family":"Hinz","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Oxford, Chemistry Research Laboratory  12 Mansfield Road OX1 3TA Oxford UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7311-1663","authenticated-orcid":false,"given":"Jose M.","family":"Goicoechea","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Oxford, Chemistry Research Laboratory  12 Mansfield Road OX1 3TA Oxford UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,11,15]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19926120113"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19956210109"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220129"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102930"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201102930"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3DT52359D"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4115693"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201501174"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC06094F"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500628"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)01267-0"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC02150B"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202590"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC04504E"},{"key":"e_1_2_2_14_1","first-page":"639","author":"Jupp A. R.","year":"2015","journal-title":"Eur. J. Inorg. Chem."},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt53569j"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403419"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201600701"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201600701"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00187"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511956"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT04012K"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.04.001"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04232"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201600903"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201600903"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308220"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308220"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305235"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305235"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402884"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402884"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409908"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409908"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC53140F"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC00963D"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201602310"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/om960929l"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/om500946e"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.5b00884"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502824w"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00344"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402031"},{"key":"e_1_2_2_37_1","unstructured":"\u03b4(119Sn)=1971\u2005ppm; see Ref.\u2005[32]."},{"key":"e_1_2_2_38_1","unstructured":"1J(31P-119Sn) coupling constants are reported as1JP-Sn."},{"key":"e_1_2_2_39_1","unstructured":"Gaussian 09 (Revision\u2005D.01) M.\u2005J. Frisch et\u2005al. 2009."},{"key":"e_1_2_2_40_1","unstructured":"Geometry optimization topological analyses frequency and NMR calculations were carried out with Gaussian\u200909 D.01 at the PBE1PBE level of theory utilizing 6-311G(d p) basis sets except for Sn for which a fully relativistic ECP and a corresponding basis set were used. Further details can be found in the Supporting Information."},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00440-X"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1999-0709"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990419)38:8<1103::AID-ANIE1103>3.0.CO;2-5"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990419)111:8<1176::AID-ANGE1176>3.0.CO;2-P"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/b709446a"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000103"},{"key":"e_1_2_2_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23266"},{"key":"e_1_2_2_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar980073b"},{"key":"e_1_2_2_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/om0604627"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1305"},{"key":"e_1_2_2_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00671-9"},{"key":"e_1_2_2_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00354a069"},{"key":"e_1_2_2_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja983999n"},{"key":"e_1_2_2_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja400219d"},{"key":"e_1_2_2_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/b212224c"},{"key":"e_1_2_2_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/om700365p"},{"key":"e_1_2_2_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9727575"},{"key":"e_1_2_2_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0257164"},{"key":"e_1_2_2_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja982717g"},{"key":"e_1_2_2_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(98)01191-7"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201609309","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201609309","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201609309","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,6]],"date-time":"2023-10-06T12:47:52Z","timestamp":1696596472000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201609309"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,11,15]]},"references-count":68,"journal-issue":{"issue":"50","published-print":{"date-parts":[[2016,12,12]]}},"alternative-id":["10.1002\/anie.201609309"],"URL":"https:\/\/doi.org\/10.1002\/anie.201609309","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,11,15]]}}}