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The unknown phosphorus analogue of cyanuric acid, P<jats:sub>3<\/jats:sub>C<jats:sub>3<\/jats:sub>(OH)<jats:sub>3<\/jats:sub>, may become an equally useful building block for phosphorus\u2010based polymers or materials which have unique properties.<jats:ext-link xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"#anie201610156-bib-0001\"\/> Herein we describe a straightforward synthesis of 2,4,6\u2010tri(hydroxy)\u20101,3,5\u2010triphosphinine and its derivatives P<jats:sub>3<\/jats:sub>C<jats:sub>3<\/jats:sub>(OR)<jats:sub>3<\/jats:sub> which have been applied as strong \u03c0\u2010acceptor \u03b7<jats:sup>6<\/jats:sup>\u2010ligands in piano stool Mo(CO)<jats:sub>3<\/jats:sub> complexes.<\/jats:p>","DOI":"10.1002\/anie.201610156","type":"journal-article","created":{"date-parts":[[2016,12,27]],"date-time":"2016-12-27T12:08:16Z","timestamp":1482840496000},"page":"1356-1360","source":"Crossref","is-referenced-by-count":66,"title":["2,4,6\u2010Tri(hydroxy)\u20101,3,5\u2010triphosphinine, P<sub>3<\/sub>C<sub>3<\/sub>(OH)<sub>3<\/sub>: The Phosphorus Analogue of Cyanuric Acid"],"prefix":"10.1002","volume":"56","author":[{"given":"Riccardo","family":"Suter","sequence":"first","affiliation":[{"name":"Department of Chemistry and Applied Biosciences ETH Zurich  8093 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanbo","family":"Mei","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Applied Biosciences ETH Zurich  8093 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew","family":"Baker","sequence":"additional","affiliation":[{"name":"Department of Chemistry and 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