{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T20:10:24Z","timestamp":1791231024640,"version":"4.1.0"},"reference-count":41,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2016,12,22]],"date-time":"2016-12-22T00:00:00Z","timestamp":1482364800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,1,19]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The directed synthesis, spectroscopic properties, and reactivity of bis(trimethylphosphine) beryllium dichloride (\n                    <jats:bold>1<\/jats:bold>\n                    ) and bis(diphenylphosphino)propane beryllium dichloride (\n                    <jats:bold>2<\/jats:bold>\n                    ) are reported, including the crystal structure of (PMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    BeCl\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    ). These four\u2010coordinate beryllium compounds can be alkylated with n\u2010butyllithium (\n                    <jats:sup>n<\/jats:sup>\n                    BuLi) to give three\u2010coordinate (Ph\n                    <jats:sub>2<\/jats:sub>\n                    PC\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    PPh\n                    <jats:sub>2<\/jats:sub>\n                    )Be\n                    <jats:sup>n<\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>3<\/jats:bold>\n                    ) and (PMe\n                    <jats:sub>3<\/jats:sub>\n                    )Be\n                    <jats:sup>n<\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>4<\/jats:bold>\n                    ). PMe\n                    <jats:sub>3<\/jats:sub>\n                    can be removed from (PMe\n                    <jats:sub>3<\/jats:sub>\n                    )Be\n                    <jats:sup>n<\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>4<\/jats:bold>\n                    ) in\u2005vacuo to yield [\n                    <jats:sup>n<\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    Be]\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>5<\/jats:bold>\n                    ). For the first time, the presence of [\n                    <jats:sup>n<\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    Be]\n                    <jats:sub>2<\/jats:sub>\n                    as a dimer in solution, which has been postulated for decades, could be observed spectroscopically. This novel, ether\u2010free pathway provides access to beryllium dialkyl compounds that have never been in contact with oxygen\u2010atom\u2010containing reagents or solvents. This \u201cfreeness from oxygen\u201d is crucial for semiconductor applications where oxygen is often unwanted and must be avoided at all costs.\n                  <\/jats:p>","DOI":"10.1002\/anie.201610956","type":"journal-article","created":{"date-parts":[[2016,12,22]],"date-time":"2016-12-22T07:48:11Z","timestamp":1482392891000},"page":"1130-1134","source":"Crossref","is-referenced-by-count":47,"title":["Beryllium Phosphine Complexes: Synthesis, Properties, and Reactivity of (PMe\n                    <sub>3<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    BeCl\n                    <sub>2<\/sub>\n                    and (Ph\n                    <sub>2<\/sub>\n                    PC\n                    <sub>3<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    PPh\n                    <sub>2<\/sub>\n                    )BeCl\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"56","author":[{"given":"Magnus R.","family":"Buchner","sequence":"first","affiliation":[{"name":"Anorganische Chemie, Nachwuchsgruppe Berylliumchemie, Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35032 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Anorganische Chemie, Nachwuchsgruppe Berylliumchemie, Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35032 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan S.","family":"Rudel","sequence":"additional","affiliation":[{"name":"Anorganische Chemie, Arbeitsgruppe Fluorchemie, Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35032 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,12,22]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601809"},{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601809"},{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1033"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.11.008"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800163"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0898-8838(09)00209-8"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902425"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51021b"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic3022968"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic402895h"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201501433"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(95)05615-V"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja304514f"},{"key":"e_1_2_2_15_1","unstructured":"\u00a0"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107836"},{"key":"e_1_2_2_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107836"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/om501314g"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900521"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200900521"},{"key":"e_1_2_2_19_1","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2542"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606244"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606244"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1150856"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000172"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.5560\/ZNB.2011.66b0055"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/j19680002651"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00720a011"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00364a005"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0248(86)90278-2"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/cs9972600101"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01154a025"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic970319t"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00043a002"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270194014368"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1744408"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/om0603114"},{"key":"e_1_2_2_36_1","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1002\/9780470147108.ch4","volume-title":"Topics 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