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The formed complex is an unusual fluorophosphorane (<jats:bold>[3\u2010F]<\/jats:bold>OTf). The multiple donor\u2013acceptor interactions of <jats:bold>3<\/jats:bold><jats:sup>2+<\/jats:sup> that are crucial for the fluoride fixation have been elucidated by quantum chemical calculation. Compound <jats:bold>[3\u2010F]<\/jats:bold>OTf can also be used as a convenient anhydrous fluoride ion source and was probed as a suitable catalyst of the silylotrifluoromethylation of various aldehydes.<\/jats:p>","DOI":"10.1002\/anie.201701570","type":"journal-article","created":{"date-parts":[[2017,5,8]],"date-time":"2017-05-08T14:22:44Z","timestamp":1494253364000},"page":"7907-7911","source":"Crossref","is-referenced-by-count":13,"title":["Selective and Reversible Fluoride Complexation from Water by a Cyclic Tri(phosphonio)methanide Dication"],"prefix":"10.1002","volume":"56","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6290-9426","authenticated-orcid":false,"given":"Sivathmeehan","family":"Yogendra","sequence":"first","affiliation":[{"name":"Department of Chemistry and Food Chemistry TU Dresden  01062 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Felix","family":"Hennersdorf","sequence":"additional","affiliation":[{"name":"Department of 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