{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T05:31:19Z","timestamp":1783402279228,"version":"3.54.6"},"reference-count":66,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2017,5,4]],"date-time":"2017-05-04T00:00:00Z","timestamp":1493856000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The activation of yellow arsenic is possible with the silylene [PhC(NtBu)<jats:sub>2<\/jats:sub>SiN(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] (<jats:bold>1<\/jats:bold>) and the disilene [(Me<jats:sub>3<\/jats:sub>Si)<jats:sub>2<\/jats:sub>N(\u03b7<jats:sup>1<\/jats:sup>\u2010Me<jats:sub>5<\/jats:sub>C<jats:sub>5<\/jats:sub>)Si=Si(\u03b7<jats:sup>1<\/jats:sup>\u2010Me<jats:sub>5<\/jats:sub>C<jats:sub>5<\/jats:sub>)N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] (<jats:bold>3<\/jats:bold>). The reaction of As<jats:sub>4<\/jats:sub>with<jats:bold>1<\/jats:bold>leads to the unprecedented As<jats:sub>10<\/jats:sub>cage compound [(LSiN(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>As<jats:sub>10<\/jats:sub>] (<jats:bold>2<\/jats:bold>; L=PhC(NtBu)<jats:sub>2<\/jats:sub>) with an As<jats:sub>7<\/jats:sub>nortricyclane core stabilized by arsasilene moieties containing silicon(II)bis(trimethylsilyl)amide substituents. In contrast, the compound [Cp*{(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>N}SiAs]<jats:sub>2<\/jats:sub>(<jats:bold>4<\/jats:bold>) containing a butterfly\u2010like diarsadisilabicyclo[1.1.0]butane unit is formed by the reaction of As<jats:sub>4<\/jats:sub>with the disilene<jats:bold>3<\/jats:bold>. Both compounds were characterized by single\u2010crystal X\u2010ray diffraction analysis, NMR spectroscopy, and mass spectrometry. The reaction outcomes demonstrate the different reaction behavior of yellow arsenic (As<jats:sub>4<\/jats:sub>) compared to white phosphorus (P<jats:sub>4<\/jats:sub>) in the reactions with the corresponding silylenes and disilenes.<\/jats:p>","DOI":"10.1002\/anie.201701740","type":"journal-article","created":{"date-parts":[[2017,5,4]],"date-time":"2017-05-04T11:13:14Z","timestamp":1493896394000},"page":"6655-6659","source":"Crossref","is-referenced-by-count":33,"title":["Different Reactivity of As<sub>4<\/sub>towards Disilenes and Silylenes"],"prefix":"10.1002","volume":"56","author":[{"given":"Andreas E.","family":"Seitz","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Eckhardt","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sakya S.","family":"Sen","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Georg-August-University Tammannstrasse 4 37077 G\u00f6ttingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"Erlebach","sequence":"additional","affiliation":[{"name":"Otto-Schott-Institut f\u00fcr Materialforschung Friedrich-Schiller-Universit\u00e4t Jena L\u00f6bdergraben 32 07743 Jena Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eugenia V.","family":"Peresypkina","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg Universit\u00e4tsstrasse 31 93040 Regensburg Germany"},{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS Ak. Lavrentiev prosp. 3 630090 Novosibirsk Russia"},{"name":"Novosibirsk State University Pirogova str. 2 630090 Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Herbert W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Georg-August-University Tammannstrasse 4 37077 G\u00f6ttingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marek","family":"Sierka","sequence":"additional","affiliation":[{"name":"Otto-Schott-Institut f\u00fcr Materialforschung Friedrich-Schiller-Universit\u00e4t Jena L\u00f6bdergraben 32 07743 Jena Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg Universit\u00e4tsstrasse 31 93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,5,4]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"Selected references:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819621d"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00036a008"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(95)00522-R"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527609350"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02274"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141474"},{"key":"e_1_2_2_10_1","unstructured":"Reviews:"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17449a"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703055"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703055"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077296u"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902344"},{"key":"e_1_2_2_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902344"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/b818396a"},{"key":"e_1_2_2_21_1","unstructured":"\u00a0"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198910381"},{"key":"e_1_2_2_22_3","doi-asserted-by":"crossref","first-page":"1087","DOI":"10.1002\/ange.19891010837","volume":"101","year":"1989","journal-title":"Angew. 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