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In a macrocycle\u2010to\u2010macrocycle transformation approach, S<jats:sub>6<\/jats:sub>\u2010corona[3]arene[3]tetrazine underwent sequential S<jats:sub>N<\/jats:sub>Ar reactions with HS\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010X\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010SH (X=S, CH<jats:sub>2<\/jats:sub>, CMe<jats:sub>2<\/jats:sub>, SO<jats:sub>2<\/jats:sub>, and O) to produce the corresponding corona[3]arene[2]tetrazines. Different corona[3]arene[2]tetrazine compounds were also constructed in a straightforward manner by a one\u2010pot three\u2010component reaction of HS\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010X\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>\u2010SH (X=S, CH<jats:sub>2<\/jats:sub>, CMe<jats:sub>2<\/jats:sub>, SO<jats:sub>2<\/jats:sub>, and O) with diethyl 2,5\u2010dimercaptoterephthalate and 2\u2005equiv of 3,6\u2010dichlorotetrazine under very mild conditions. All corona[5]arenes adopted 1,2,4\u2010alternate conformational structures in the crystalline state yielding similar nearly regular pentagonal cavities. Both the cavity size and the electronic property of the acquired macrocycles were fine\u2010tuned by the nature of the bridging element X.<\/jats:p>","DOI":"10.1002\/anie.201703008","type":"journal-article","created":{"date-parts":[[2017,5,15]],"date-time":"2017-05-15T09:59:06Z","timestamp":1494842346000},"page":"7151-7155","source":"Crossref","is-referenced-by-count":45,"title":["Corona[5]arenes Accessed by a Macrocycle\u2010to\u2010Macrocycle Transformation Route and a One\u2010Pot Three\u2010Component Reaction"],"prefix":"10.1002","volume":"56","author":[{"given":"Zhi\u2010Chen","family":"Wu","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing\u2010Hui","family":"Guo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7112-0657","authenticated-orcid":false,"given":"Mei\u2010Xiang","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,5,15]]},"reference":[{"key":"e_1_2_2_1_1","volume-title":"Comprehensive Supramolecular Chemistry","author":"Lehn J.-M.","year":"1996"},{"key":"e_1_2_2_2_1","volume-title":"Core Concepts in Supramolecular Chemistry and Nanochemistry","author":"Steed J. 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