{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,2]],"date-time":"2026-04-02T09:59:11Z","timestamp":1775123951039,"version":"3.50.1"},"reference-count":48,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2017,6,20]],"date-time":"2017-06-20T00:00:00Z","timestamp":1497916800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,7,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>[Ph<jats:sub>4<\/jats:sub>P]<jats:sub>2<\/jats:sub>[Be(N<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>] (<jats:bold>1<\/jats:bold>) and [PNP]<jats:sub>2<\/jats:sub>[Be(N<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>] (<jats:bold>2<\/jats:bold>; PNP=Ph<jats:sub>3<\/jats:sub>PNPPh<jats:sub>3<\/jats:sub>) were synthesized by reacting Be(N<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> with [Ph<jats:sub>4<\/jats:sub>P]N<jats:sub>3<\/jats:sub> and [PNP]N<jats:sub>3<\/jats:sub>. Compound <jats:bold>1<\/jats:bold> represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> were investigated by quantum\u2010chemical calculations (NPA, ELF, LOL).<\/jats:p>","DOI":"10.1002\/anie.201703147","type":"journal-article","created":{"date-parts":[[2017,5,29]],"date-time":"2017-05-29T11:27:04Z","timestamp":1496057224000},"page":"8559-8563","source":"Crossref","is-referenced-by-count":40,"title":["Synthesis, Solid\u2010State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide"],"prefix":"10.1002","volume":"56","author":[{"given":"Dominik","family":"Naglav","sequence":"first","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Briac","family":"Tobey","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Benjamin","family":"Lyhs","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Beate","family":"R\u00f6mer","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dieter","family":"Bl\u00e4ser","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christoph","family":"W\u00f6lper","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Georg","family":"Jansen","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2896-4488","authenticated-orcid":false,"given":"Stephan","family":"Schulz","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide) University of Duisburg-Essen  Universit\u00e4tsstrasse 5\u20137, S07 S03 C30 45117 Essen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,6,20]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","first-page":"502","volume":"9","author":"Wiberg E.","year":"1954","journal-title":"Z. 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