{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:30:16Z","timestamp":1786977016054,"version":"build-2736575974"},"reference-count":62,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2017,6,8]],"date-time":"2017-06-08T00:00:00Z","timestamp":1496880000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100011264","name":"FP7 People: Marie-Curie Actions","doi-asserted-by":"crossref","award":["317404"],"award-info":[{"award-number":["317404"]}],"id":[{"id":"10.13039\/100011264","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,6,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Phosphinidenes [R\u2010P] are convenient P\n                    <jats:sub>1<\/jats:sub>\n                    building blocks for the synthesis of a plethora of organophosphorus compounds. Thus far, transition\u2010metal\u2010complexed phosphinidenes have been used for their singlet ground\u2010state reactivity to promote selective addition and insertion reactions. One disadvantage of this approach is that after transfer of the P\n                    <jats:sub>1<\/jats:sub>\n                    moiety to the substrate, a challenging demetallation step is required to provide the free phosphine. We report a simple method that enables the Lewis acid promoted transfer of phenylphosphinidene, [PhP], from NHC=PPh adducts (NHC=N\u2010heterocyclic carbene) to various substrates to produce directly uncoordinated phosphorus heterocycles that are difficult to obtain otherwise.\n                  <\/jats:p>","DOI":"10.1002\/anie.201703672","type":"journal-article","created":{"date-parts":[[2017,5,15]],"date-time":"2017-05-15T14:46:40Z","timestamp":1494859600000},"page":"7948-7951","source":"Crossref","is-referenced-by-count":60,"title":["Facile Phenylphosphinidene Transfer Reactions from Carbene\u2013Phosphinidene Zinc Complexes"],"prefix":"10.1002","volume":"56","author":[{"given":"Tetiana","family":"Krachko","sequence":"first","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904, PO Box 94157 1090 GD Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mark","family":"Bispinghoff","sequence":"additional","affiliation":[{"name":"Laboratory of Inorganic Chemistry ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aaron M.","family":"Tondreau","sequence":"additional","affiliation":[{"name":"Laboratory of Inorganic Chemistry ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel","family":"Stein","sequence":"additional","affiliation":[{"name":"Laboratory of Inorganic Chemistry ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew","family":"Baker","sequence":"additional","affiliation":[{"name":"Laboratory of Inorganic Chemistry ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas W.","family":"Ehlers","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904, PO Box 94157 1090 GD Amsterdam The Netherlands"},{"name":"Department of Chemistry Science Faculty University of Johannesburg  PO Box 254, Auckland Park Johannesburg South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7818-7766","authenticated-orcid":false,"given":"J. Chris","family":"Slootweg","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904, PO Box 94157 1090 GD Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hansj\u00f6rg","family":"Gr\u00fctzmacher","sequence":"additional","affiliation":[{"name":"Laboratory of Inorganic Chemistry ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,6,8]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/b11152"},{"key":"e_1_2_2_3_2","first-page":"15","volume-title":"Science of Synthesis, Vol.\u200542","author":"Slootweg J. C.","year":"2009"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/1522-2675(20011017)84:10<2938::AID-HLCA2938>3.0.CO;2-P"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-46100-0_4"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200204)2002:7<1127::AID-EJOC1127>3.0.CO;2-X"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905689"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905689"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611196"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611196"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja306902j"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4072699"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200500454"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/a700296c"},{"key":"e_1_2_2_14_1","unstructured":"CCDC\u2005923521 (1) 1523933 (2) 1523907 (3) 1523934 (4) 1523939 (5) 1523936 (6) 1523935 (8) and 1523941 (10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge fromThe Cambridge Crystallographic Data Centre. For the experimental details of the X-ray crystal structure determinations see the Supporting Information."},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201500952"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209109"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209109"},{"key":"e_1_2_2_17_1","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)01118-4"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC45134H"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic970174q"},{"key":"e_1_2_2_21_1","unstructured":"Carbene\u2013phenylphosphinidene adducts have been prepared by using free carbenes and (PPh)5:"},{"key":"e_1_2_2_22_2","unstructured":"Ref.\u2009[12];"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1997.143"},{"key":"e_1_2_2_24_2","unstructured":"ref.\u2009[10]; using alkali metal tetraphosphanediides see:"},{"key":"e_1_2_2_25_2","unstructured":"ref.\u2009[9]; using primary phosphines see:"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508303"},{"key":"e_1_2_2_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201508303"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC02517F"},{"key":"e_1_2_2_28_1","unstructured":"See the Supporting Information for further details."},{"key":"e_1_2_2_29_1","unstructured":"So far only 1:1 complexes have been reported:"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3NJ01416A"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201600483"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT03285C"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201502208"},{"key":"e_1_2_2_34_1","unstructured":"Typical alkynes alkenes and dienes did not exhibit any reactivity toward3. We investigated the reactions ofMeNHC=PPh (1) directly with organic electrophiles (see the Supporting Information for details)."},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1080\/03086648108078271"},{"key":"e_1_2_2_36_1","unstructured":"Zinc complexes of NHCs have been shown to be catalytically active in a number of processes:"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201303968"},{"key":"e_1_2_2_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201303968"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc22240c"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201300749"},{"key":"e_1_2_2_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201300749"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/om401060u"},{"key":"e_1_2_2_41_1","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1270071003"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/prac.19723140109"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102404"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201102404"},{"key":"e_1_2_2_45_1","unstructured":"\u00a0"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2013.07.076"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100778f"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00081a021"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201302014"},{"key":"e_1_2_2_50_1","unstructured":"Selected reviews:"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc51174j"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201302715"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic502231m"},{"key":"e_1_2_2_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC53140F"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201703672","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201703672","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,16]],"date-time":"2023-09-16T03:56:46Z","timestamp":1694836606000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201703672"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,6,8]]},"references-count":62,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2017,6,26]]}},"alternative-id":["10.1002\/anie.201703672"],"URL":"https:\/\/doi.org\/10.1002\/anie.201703672","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,6,8]]}}}