{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T16:22:59Z","timestamp":1788798179888,"version":"build-2803163510"},"reference-count":62,"publisher":"Wiley","issue":"39","license":[{"start":{"date-parts":[[2017,8,16]],"date-time":"2017-08-16T00:00:00Z","timestamp":1502841600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21421005, 21531001 and 21501041"],"award-info":[{"award-number":["21421005, 21531001 and 21501041"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Solar production of hydrogen by consuming low\u2010value waste products is an attractive pathway that has both economic and environmental benefits. Inspired by the reactive pocket of enzymes, a synthetic platform to combine photocatalytic hydrogen evolution with sulfide oxidation in a one\u2010pot process via control over the location of the electron\u2010transfer steps is developed. The redox\u2010active coordination vessel Ni\u2010<jats:bold>TFT<\/jats:bold>, which has an octahedral pocket, encapsulates an organic dye to pre\u2010organize for photocatalytic proton reduction via an oxidative quenching pathway using the nickel corners as catalysts, generating molecular hydrogen and the oxidized dye. The oxidized dye is displaced by a neutral dye and oxidizes sulfide once outside the pocket to give element sulfur. The overall reaction constitutes hydrogen sulfide splitting, forming molecular hydrogen and elemental sulfur, which is analogous to the water\u2010splitting reaction.<\/jats:p>","DOI":"10.1002\/anie.201704327","type":"journal-article","created":{"date-parts":[[2017,7,19]],"date-time":"2017-07-19T12:16:07Z","timestamp":1500466567000},"page":"11759-11763","source":"Crossref","is-referenced-by-count":72,"title":["Control of Redox Events by Dye Encapsulation Applied to Light\u2010Driven Splitting of Hydrogen Sulfide"],"prefix":"10.1002","volume":"56","author":[{"given":"Xu","family":"Jing","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116024 China"},{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiduo","family":"Chang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joost N. H.","family":"Reek","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Science University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunying","family":"Duan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116024 China"},{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,8,16]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.05.011"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar5004175"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60378D"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr1002326"},{"key":"e_1_2_2_6_1","unstructured":"For Reviews see:"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00192C"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60037H"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805340"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805340"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400010v"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35123D"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.744"},{"key":"e_1_2_2_13_1","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01925"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1531"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2503"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3670"},{"key":"e_1_2_2_18_1","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1124985"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000380"},{"key":"e_1_2_2_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000380"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja412582k"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad3087"},{"key":"e_1_2_2_23_1","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04609"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b06317"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3067594"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00832"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201504975"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0809666106"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/b306813g"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-3199(97)00002-5"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01772"},{"key":"e_1_2_2_35_1","unstructured":"\u00a0"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2016.04.010"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400571"},{"key":"e_1_2_2_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400571"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/0378-3820(94)00085-8"},{"key":"e_1_2_2_39_1","first-page":"1771","author":"Mallegol T.","year":"2005","journal-title":"Synthesis"},{"key":"e_1_2_2_40_1","unstructured":"Data for Ni-TFT C154H236N58Ni6O27S12 Mr=4068.99 Hexagonal space groupR3 dark-red block a=22.521(1) c=47.501(5)\u2005\u00c5 V=20865(3)\u2005\u00c53 Z=3 \u03c1calcd=0.971\u2005g\u2009cm\u22123 T=180(2)\u2005K \u03bc(Mo-K\u03b1)=0.543\u2005mm\u22121. 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