{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T16:32:42Z","timestamp":1792081962932,"version":"4.4.0"},"reference-count":55,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2018,6,21]],"date-time":"2018-06-21T00:00:00Z","timestamp":1529539200000},"content-version":"am","delay-in-days":337,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2017,7,19]],"date-time":"2017-07-19T00:00:00Z","timestamp":1500422400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-AC05-00OR22725"],"award-info":[{"award-number":["DE-AC05-00OR22725"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-AC02-05CH11231"],"award-info":[{"award-number":["DE-AC02-05CH11231"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,8,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Although perovskites have been widely used in catalysis, tuning of their surface termination to control reaction selectivity has not been well established. In this study, we employed multiple surface\u2010sensitive techniques to characterize the surface termination (one aspect of surface reconstruction) of SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    (STO) after thermal pretreatment (Sr enrichment) and chemical etching (Ti enrichment). We show, by using the conversion of 2\u2010propanol as a probe reaction, that the surface termination of STO can be controlled to greatly tune catalytic acid\/base properties and consequently the reaction selectivity over a wide range, which is not possible with single\u2010metal oxides, either SrO or TiO\n                    <jats:sub>2<\/jats:sub>\n                    . Density functional theory (DFT) calculations explain well the selectivity tuning and reaction mechanism on STO with different surface termination. Similar catalytic tunability was also observed on BaZrO\n                    <jats:sub>3<\/jats:sub>\n                    , thus highlighting the generality of the findings of this study.\n                  <\/jats:p>","DOI":"10.1002\/anie.201704656","type":"journal-article","created":{"date-parts":[[2017,6,21]],"date-time":"2017-06-21T12:48:39Z","timestamp":1498049319000},"page":"9820-9824","source":"Crossref","is-referenced-by-count":56,"title":["Controlling Reaction Selectivity through the Surface Termination of Perovskite Catalysts"],"prefix":"10.1002","volume":"56","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6507-6183","authenticated-orcid":false,"given":"Felipe","family":"Polo\u2010Garzon","sequence":"first","affiliation":[{"name":"Chemical Sciences Division and Center for Nanophase Materials Sciences Oak Ridge National Laboratory  Oak Ridge TN 37831 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