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Chemical functionalizations of these resulting azacyclic compounds afforded various oxygenated tetrahydroquinolines which are present as the cores of many bioactive molecules. With the same reactants, a new relay catalysis using gold and zinc(II) catalysts affords highly oxygenated tetrahydroquinoline derivatives stereoselectively.<\/jats:p>","DOI":"10.1002\/anie.201707423","type":"journal-article","created":{"date-parts":[[2017,8,14]],"date-time":"2017-08-14T03:16:33Z","timestamp":1502680593000},"page":"12736-12740","source":"Crossref","is-referenced-by-count":111,"title":["Gold\u2010Catalyzed [4+2] Annulation\/Cyclization Cascades of Benzisoxazoles with Propiolate Derivatives to Access Highly Oxygenated Tetrahydroquinolines"],"prefix":"10.1002","volume":"56","author":[{"given":"Rajkumar Lalji","family":"Sahani","sequence":"first","affiliation":[{"name":"Department of Chemistry National Tsing-Hua University  Hsinchu Taiwan, ROC"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2011-8124","authenticated-orcid":false,"given":"Rai\u2010Shung","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Tsing-Hua University  Hsinchu Taiwan, ROC"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,8,30]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"See selected reviews:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100307m"},{"key":"e_1_2_2_3_2","first-page":"666","volume-title":"Microbial Pathogens and Strategies for Combating Them: Science Technology and Educations, Vol.\u20051","author":"Mel\u00e9ndez Gomez C. 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