{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T13:21:30Z","timestamp":1773840090483,"version":"3.50.1"},"reference-count":88,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2017,9,5]],"date-time":"2017-09-05T00:00:00Z","timestamp":1504569600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Sche 384\/30-2"],"award-info":[{"award-number":["Sche 384\/30-2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,10,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report on the synthesis and characterization of mixed pnictogenylboranes. The substitution of the Lewis base SMe<jats:sub>2<\/jats:sub> in (OC)<jats:sub>5<\/jats:sub>W\u2013PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u2013SMe<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>) by different pnictogenylboranes ER<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u2013LB (E=P, As, Sb) leads to the Lewis acid\/base stabilized butane analogue (OC)<jats:sub>5<\/jats:sub>W\u2013PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>ER<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u2013LB (<jats:bold>3\u2009a<\/jats:bold>,\u2009<jats:bold>b<\/jats:bold>: E=P; R=H, SiMe<jats:sub>3<\/jats:sub>; LB=NMe<jats:sub>3<\/jats:sub>; <jats:bold>4\u2009a<\/jats:bold>,\u2009<jats:bold>b<\/jats:bold>: E=As; R=H, SiMe<jats:sub>3<\/jats:sub>; LB=NMe<jats:sub>3<\/jats:sub>; <jats:bold>5<\/jats:bold>: E=Sb; R=SiMe<jats:sub>3<\/jats:sub>; LB=NHC<jats:sup>Me<\/jats:sup>). All of these compounds were characterized by single\u2010crystal X\u2010ray structure analysis, mass spectrometry, NMR, and IR spectroscopy. In addition, the very unstable phosphanylborane chain PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u2013NMe<jats:sub>3<\/jats:sub> (<jats:bold>1<\/jats:bold>) was synthesized. DFT calculations provide insight into the thermodynamics of these reactions.<\/jats:p>","DOI":"10.1002\/anie.201707436","type":"journal-article","created":{"date-parts":[[2017,8,7]],"date-time":"2017-08-07T14:16:37Z","timestamp":1502115397000},"page":"12783-12787","source":"Crossref","is-referenced-by-count":20,"title":["A Convenient Route to Mixed Pnictogenylboranes"],"prefix":"10.1002","volume":"56","author":[{"given":"Oliver","family":"Hegen","sequence":"first","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"Marquardt","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1932-6647","authenticated-orcid":false,"given":"Alexey 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